Uklanjanje zagađenja dizela sorpcijom na biočađi – podrška remedijaciji kontaminiranih voda Original scientific paper
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Prečišćavanje voda zagađenih dizelom predstavlja jedan od glavnih izazova u tretmanu otpadnih voda. Frakcija rastvorna u vodi (engl. WSF) je naročito važna, obzirom na njenu direktnu toksičnost po vodene organizme, kao i na granične vrednosti postavljene zakonskom regulativom. Sorbenti na bazi biočađi privlače značajnu pažnju istraživača, obzirom na njihovo ekonomski isplativo poreklo i osobine koje doprinose visokim sorpcionim kapacitetima.U ovom radu prikazana je sinteza i karakteristike biočađi napravljene od otpadnog lignoceluloznoog materijala koštice breskve, i ispitana je njena moguća primena kao sorbenta u uklanjanju rastvorne frakcije dizela iz kontaminiranih voda. Fizičko-hemijske karakteristike biočađi analizirane su primenom SEM, BET, i FTIR tehnike, zajedno sa elementarnom organskom analizom. Karakterizacija biočađi koštice breskve pokazala je multiporoznu strukturu velike specifične površine (159,1 m2 g-1) sa prosečnom veličinom pora 2,66 nm. FTIR rezultati ukazali su na veće prisustvo aromatičnih jedinjenja u biočađi u odnosu na nativni uzorak. Sorpcioni eksperimenti izvedeni u šaržnom sistemu pokazali su da je procenat uklanjanja WSF dizela veći od 95% inicijalne koncentracije, uz postizanje ravnoteže nakon 5 h. Sorpcioni mehanizam je opisan kao višeslojna hemisorpcija, fitovan Frojndlihovim modelom, što je i potvrđeno modelom kinetike pseudo-drugog reda. Ekotoksikološki testovi su pokazali smanjenje ekotoksičnosti na Aliivibrio fischeri nakon tretmana voda uzorkom biočađi.
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