The use of PWHM and Mie methods in the estimation of colloidal silver particle size obtained by chemical precipitation with sodium borohydride
Bočna strana članka
Glavni sadržaj članka
Apstrakt
Unique antibacterial properties of silver have been known since the time of Egyptian pharaohs. With the discovery of antibiotics at the beginning of the twentieth century, silver is mostly pushed out from conventional medicine. However, with the excessive use of antibiotics, antibiotic-resistant super bacteria have appeared. Therefore, there is an increased interest in studying the antibacterial effects of colloidal silver. In this paper, the influence of various concentrations of silver nitrate on formation of colloidal silver particles in the solution was investigated. Colloidal silver was prepared by a chemical precipitation method using sodium borohydride as a reducing agent. As influence factors, color of the solution, Tyndall effect, UV/Vis absorption, and nanoparticle size estimated by PWHM (Peak Width at Half Maximum) and Mie methods were used. By increasing the silver concentration, color of the solution ranged from light yellow to dark yellow. All solutions showed Tyndall's effect equally. By the UV/Vis analysis it was found that the solutions absorbed radiation in the wavelength range 390-402 nm, and the intensity increased with increasing silver nitrate concentrations. By the PWHM and Mie methods silver nanoparticle sizes were estimated in the range 12-20 nm.
Detalji članka
Broj časopisa
Rubrika
Kada je rukopis prihvaćen za objavlјivanje, autori prenose autorska prava na izdavača. U slučaju da rukopis ne bude prihvaćen za štampu u časopisu, autori zadržavaju sva prava.
Na izdavača se prenose sledeća prava na rukopis, uklјučujući i dodatne materijale, i sve delove, izvode ili elemente rukopisa:
- pravo da reprodukuje i distribuira rukopis u štampanom obliku, uklјučujući i štampanje na zahtev;
- pravo na štampanje probnih primeraka, reprint i specijalnih izdanja rukopisa;
- pravo da rukopis prevede na druge jezike;
- pravo da rukopis reprodukuje koristeći fotomehanička ili slična sredstva, uklјučujući, ali ne ograničavajući se na fotokopiranje, i pravo da distribuira ove kopije;
- pravo da rukopis reprodukuje i distribuira elektronski ili optički koristeći sve nosioce podataka ili medija za pohranjivanje, a naročito u mašinski čitlјivoj/digitalizovanoj formi na nosačima podataka kao što su hard disk, CD-ROM, DVD, Blu-ray Disc (BD), mini disk, trake sa podacima, i pravo da reprodukuje i distribuira rukopis sa tih prenosnika podataka;
- pravo da sačuva rukopis u bazama podataka, uklјučujući i onlajn baze podataka, kao i pravo prenosa rukopisa u svim tehničkim sistemima i režimima;
- pravo da rukopis učini dostupnim javnosti ili zatvorenim grupama korisnika na osnovu pojedinačnih zahteva za upotrebu na monitoru ili drugim čitačima (uklјučujući i čitače elektonskih knjiga), i u štampanoj formi za korisnike, bilo putem interneta, onlajn servisa, ili putem internih ili eksternih mreža.
Kako citirati
Reference
Tien DC, Tseng KH, Liao CY, Huang JC, Tsung TT. Discovery of ionic silver in silver nanoparticle suspension fabricated by arc discharge method. J. Alloys Comp. 2008; 463(1-2): 408-411.
Panáček A, Kvítek L, Prucek R, Kolar M, Vecerova R, Pizúrova N, Sharma VK, Nevecna T, Zboril R. Silver colloid nanoparticles: Synthesis, characterization, and their antibacterial activity. J. Phys. Chem. 2006; 110 B: 16248-16253.
Jegatha Christy A, Kevin A, Nehru LC, Umadevi M. Optical, structural and morphological properties of silver nanoparticles and their antimicrobial activity. Inter. J. Chem. Tech. Res. 2015; 7(3): 1191-1197.
Mikac L, Ivanda M, Gotić M, Mihelj T, Horvat L. Synthesis and characterization of silver colloidal nanoparticles with different coatings for SERS application. J. Nanopart. Res. 2014; 16: 2748-2761.
Kim KY, Choi YT, Seo DJ, Park SB. Preparation of silver colloid and enhancement of dispersion stability in organic solvent. Mater. Chem. Phys. 2004; 88(2-3): 377-382.
Ismail MM, Abd Ulaziz SM. Spectral study of silver nanoparticles prepared by chemical method. Engin. Tech. J. 2014; 32(5): 869-876.
Zhai X, Efrima S. Reduction of silver ions to a colloid by eriochrome black T. J. Phys. Chem. 1996; 100(5): 1779-1785.
Iravani S, Korbekandi H, Mirmohammadi SV, Zolfaghari B. Synthesis of silver nanoparticles: chemical, physical and biological methods. Res. Pharm. Sci. 2014; 6(9): 385-406.
Šileikaite A, Puišo J, Prosyčevas IS, Tamulevičius S. Investigation of silver nanoparticles formation kinetics during reduction of silver nitrate with sodium citrate. Mater. Sci. 2009; 15(1): 21-27.
Kelkawi AHA, Kajani AA, Bordbar AK. Green synthesis of silver nanoparticles using Mentha pulegium and investigation of their antibacterial, antifungal and anticancer activity. IET Nanobiotech. 2017; 11(4): 370-376.
Bezić A. Priprava koloidnog srebra kemijskom redukcijom pomoću NaBH4 i prirodnim reducensima. Bachelor Thesis, University of Split, Split, 2015. (in Croatian)
Meshram SM, Bonde SR, Gupta IR, Gade AK, Rai MK. Green synthesis of silver nanoparticles using white sugar. IET Nanobiotech. 2013; 7(1): 28-32.
Murali Mohan Y, Mohana Raju K, Sambasivudu K, Singh S, Sreedhar B. Preparation of acacia-stabilized silver nanoparticles. A Green Approach. J. Appl. Polym. Sci. 2007; 165(5): 3375-3381.
Hema JA, Malaka R, Muthukumarasamy NP, Sambandam A, Subramanian S, Sevanan M. Green synthesis of silver nanoparticles using Zea mays and exploration of its biological applications. IET Nanobiotech. 2016; 10(5): 288-294.
Bhat PN, Nivedita S, Subrata R. Use of sericin of Bombyx mori in the synthesis of silver nanoparticles, their characterization and application. Indian J. Fibre Text. Res. 2011; 36: 168-171.
Cheviron P, Gouanvé F, Espuche E. Green synthesis of colloid silver nanoparticles and resulting biodegradable starch/silver nanocomposites. Carbohydrate Polym. 2014; 108: 291-298.
Tai CY, Wang YH, Liu HS. A green process for preparing silver nanoparticles using spinning disk reactor. AIChE J. 2008; 54(2): 445-452.
Jha AK, Prasad K, Kumar V, Prasad K. Biosynthesis of silver nanoparticles using eclipta leaf. Biotech. Prog. 2009; 25(5): 1476–1479.
Lopez-Miranda JL, Vazquez M, Fletes N, Esparza R, Rosas G. Biosynthesis of silver nanoparticles using a Tamarix gallica leaf extract and their antibacterial activity. Materials Letters. 2016; 176(1): 285-289.
Gurunathan S, Kalishwaralal K, Vaidyanathan R, Deepak V, Kumar Pandian SR, Muniyandi J, Hariharan N, Hyun Eom S. Biosynthesis, purification and characterization of silver nanoparticles using Escherichia coli. Colloids and Surfaces B: Biointerfaces. 2009; 74(1): 328-335.
Kontogeorgis GM, Kiil S. Introduction to applied colloid and surface chemistry. Chichester, John Wiley & Sons; 2016.
Mulfinger L, Solomon SD, Bahadory M, Jeyarajasingam AV, Rutkowsky SA, Boritz C. Synthesis and study of silver nanoparticlesJ. Chem. Educ. 2007, 84, 322-325.
Song KC, Lee SM, Park TS, Lee BS. Preparation of colloidal silver nanoparticles by chemical reduction method. Korean J. Chem. Engin. 2009; 26(1): 153-155.
Goharshadi E, Azizi-Toupkanloo H. Silver colloid nanoparticles: Ultrasound-assisted synthesis, electrical and rheological properties. Powder Tech. 2013; 237: 97-101.
Fu Q, Sun W. Mie theory for light scattering by a spherical particle in an absorbing medium. Appl. Opt. 2001; 40: 1354-1361.
Bohren CF, Huffman DR. Absorption and scattering of light by small particles. New York, Wiley-Interscience; 1983.
Van Hyning DL, Zukoski CF. Formation mechanisms and aggregation behavior of borohydride reduced silver particles. Langmuir. 1998; 14(24): 7034–7046.
Liu J, Lee JB, Kim DH, Kim Y. Preparation of high concentration of silver colloidal nanoparticles in layered laponite sol. Colloids Surf A. 2007; 302: 276–279.
Mulfinger L, Solomon SD, Bahadory M, Jeyarajasingam AV, Rutkowsky SA, Boritz C. Synthesis and study of colloidal silver. J. Chem. Educ. 2007; 84(2): 322-325.
Bonsak J, Mayandi J, Thøgersen A, Marstein ES, Mahalingam U. Chemical synthesis of silver nanoparticles for solar cell applications. Physica Status Solidi C. 2011; 3(8): 924–927.
Laven P., http://www.philiplaven.com/mieplot.htm Acessed June 23rd 2019.