Fentonov tip oksidativne degradacije boje Orange G i binarnih smeša boja pomoću Oksona® aktiviranog katalizatorima na bazi aluminijum oksida dopiranih kobaltom Naučni rad
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Dva kobaltom dopirana katalizatora na bazi aluminijum oksida, sa ra zličitim teksturalnim i strukturnim karakteristikama, dobijena su sol-gel postupkom sinteze, nakon koje su uzorci žareni na tempreturi od 1000 °C odnosno 1100 °C. Dobijeni materijali su ispitani kao katalizatori u procesu degradacije anjonske tekstilne boje Orange G (OG) uz korišćenje Oksona kao prekursora sulfatnih anjon radikala, koji su glavna oksidativna vrsta. Ispitan je uticaj temperature i početnog pH na efikasnost degradacije, i uočeno je da porast temperature povećava brzinu reakcije. Maksimalna efikasnost degradacijeje dobijena na 60 °C. Primenjeni su različiti kinetički modeli i pokazalo se da kinetički model pseudo-prvog reda najbolje opisuje kinetiku ispitanog procesa. Takođe je za oba katalizatora utvrđeno da je optimalna vrednost pH za ispitivanu reakciju u oblasti blizu neutralne. Koegzistirajući katjoni (Ca2+, Mg2+, K+ and Na+) i anjoni Clˉ and H2PO4ˉ su ubrzavali degradaciju OG, dok su je anjoni NO3ˉ, SO42ˉ i HCO3ˉ usporavali. Katalizatori su se pokazali efikasnii u degradaciji boja: metilensko plavo, osnovno plavo 41 i boje “Remazol brilliant blue”, kao i u degradaciji boja u binarnim smešama. Ipak, razlike u strukturnim i teksturalnim svojstvima su uticale na razlike u katalitičkoj efikasnosti ova dva katalizatora.
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Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-47/2023-01/200026
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