Valorizacija energetske biljke Arundo donax uzgajane u Srbiji za biosorpciju jona kobalta iz vodenog rastvora: kinetički aspekt Naučni rad
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Joni metala se mogu eliminisati iz vodenih rastvora korišćenjem biosorbenata, materijala dobijenih iz biljne biomase. U ovoj studiji, istraživana je potencijalna upotreba Arundo donax stabljike kao jeftinog, prirodnog biosorbenta za uklanjanje jona kobalta (Co2+) iz vodenog rastvora. Arundo donax stabljika je karakterisana analizom hemijskog sastava (u pogledu sadržaja celuloze, hemiceluloze i lignina), tačke nultog naelektrisanja (pHPZC), skenirajućom elektronskom mikroskopijom (SEM), energetskom disperzionom spektroskopijom x–zraka (EDS), rendgenskom difrakcionom analizom (XRD) i infracrvenom spektroskopijom sa Furijeovom transformacijom (FTIR). Istraživanja kinetike su pokazala da se vezana količina Co2+ jona na Arundo donax stabljici povećavala sa povećanjem vremena kontakta dostižući stanje ravnoteže posle 360 min. Primenjeni su kinetički modeli pseudo-prvog reda, pseudo-drugog reda, Elovičev model i model unutrašnje difuzije za opisivanje eksperimentalnih podataka. Najbolja predviđanja su dobijena primenom kinetičkog modela pseudo-prvog reda uz najveću vrednost koeficijenta determinacije R2 = 0.996, i najmanju vrednost c2 = 0.757. Nalazi ove studije mogu se primeniti na projektovanje šaržnih biosorpcionih sistema za uklanjanje jona kobalta iz vodenih rastvora.
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Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-47/2023-14/200026
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