Fotodegradacija tiofanat-metila pod dejstvom svetlosti koja imitira sunčevo zračenje korišćenjem novih kompozitnih fotokatalizatora Naučni rad
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Ovaj rad ima za cilj da prikaže uticaj prisustva nanočestica na površini titanijum (IV) oksida na fotokatalitički kapacitet razlaganja prisutnog organskog polutanta pod dejstvom simulirane sunčeve svetlosti. U tu svrhu, površina rutil titanijum (IV) oksida (r-TiO2) dekorisana je železo vanadatom (FeVO4/r-TiO2) i vanadijumom supstituisanim getitom (Fe1-xVxOOH/r-TiO2). Dobijeni kompoziti su okarakterisani primenom skenirajuće elektronske mikroskopije u emisionom polju uz energetsku disperzionu spektroskopiju, difrakcije X-zraka na sprašenim uzorcima, adsorpcijom azota na tački ključanja primenom Brunauer-Emet-Teler metodologije, infracrvene spektroskopije sa Furijeovom transformacijom u modu smanjene totalne refleksije i spektroskopije difuzne refleksije ultraljubičasto-vidljivog zračenja. Oba fotokatalizatora su pokazala veću fotoaktivnost od komercijalnog r-TiO2 za degradaciju tiofanat-metila (2,5 h umesto 5 h). Tokom ispitivanja ispitivani su faktori kao što su vreme zračenja, količina katalizatora i koncentracija pesticida. Takođe, fotokatalizatori su primenjeni u uzastopnim višecikličnim testovima degradacije da bi se ispitala njihova efikasnost tokom dužeg vremena eksploatacije. Praćenje brzine uklanjanja vršeno je pomoću spektrometrije ultraljubičastog/vidljivog zračenja i tečne hromatografije visokih performansi. Pomoćni alat za proveru potpunosti razgradnje fungicida jeste određivanje hemijske potrošnje kiseonika nakon svake faze tretmana. Koncentracija posmatrane zagađujuće materije u tretiranim uzorcima je ispod propisanog zakonskog nivoa. Pripremljeni materijali su pokazali veliku stabilnost, postojanost i fotokatalitičku aktivnost što predstavlja dobru osnovu za primenu ovog procesa u realnim postrojenjima za prečišćavanje otpadnih voda.
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Ovaj rad je pod Creative Commons Aуторство-Nekomercijalno-Bez prerade 4.0 Internacionalna licenca.
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Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja
Grant numbers 451-03-47/2023-01/200023; 451-03-9/2023-14/200017; 451-03-47/2023-01/200135;451-03-47/2023-01/200023;451-03-9/2023-14/200017;451-03-47/2023-01/200135
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