Effects of production conditions on the properties of limestone briquettes aimed for acid soil liming Original scientific paper

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Vladimir Jovanović
Dragana Nišić
Vladimir Milisavljević
Dejan Todorović
Dragan Radulović
Branislav Ivošević
Sonja Milićević


This paper presents the results of experiments performed to determine how the quantity of the binder (bentonite) and the parameters of the laboratory roll press affect the quality of the briquettes obtained from limestone powder. These experiments aim to examine the conditions in which limestone briquettes are formed and to determine their use for agricultural purposes. During the experiments various mass fractions of bentonite was added to limestone (from 1 to 10 %), while the force of roll press drums ranged from 2 to 25 kN. The briquettes have been tested by applying scanning electron microscopy (SEM), differential thermal and thermo-gravimetric (DTA/TG) analyses, X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR). Bentonite distribution was found to be uniform within the compact briquette structure. Formation of new compounds was not evidenced. The experiments also demonstrated that during briquetting, limestone properties remain unchanged, the changes are only physical, water solubility is not reduced, mechanical properties (impact resistance, compressive strength and abrasion resistance) are satisfactory by the transport and storage terms if the binder mass fraction is over 5% and the briquetting force exceeds 10kN and finally there is no loss due to wind dispersal during application. The only downside of the “green” briquettes obtained is the time required for their complete disintegration if totally immersed in water.


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Jovanović, V., Nišić, D., Milisavljević, V., Todorović, D., Radulović, D., Ivošević, B., & Milićević, S. (2022). Effects of production conditions on the properties of limestone briquettes aimed for acid soil liming: Original scientific paper. HEMIJSKA INDUSTRIJA, 76(2), 97–107. https://doi.org/10.2298/HEMIND220211011J
Material Enginerring - Inorganic materials

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Oh S, Hyun CU, Park HD. Near-Infrared Spectroscopy of Limestone Ore for CaO Estimation under Dry and Wet Conditions. Minerals 2017; 7(10): 193 https://doi.org/10.3390/min7100193

Carvalho EAD, Brinck V, Campos ARD, Campos VRD. Aglomeração. Parte I: Briquetagem, 5th ed, Comunicação Técnica elaborada para o LivroTratamento de Minérios, Rio de Janeiro, 2010; 683-750 (in Portuguese)

Lee H, Kim K, Kim J, You K, Lee H. Breakage Characteristics of Heat-Treated Limestone Determined via Kinetic Modeling. Minerals 2018; 8(1): 18 https://doi.org/10.3390/min8010018

McLaughlin MJ, Zarcinas BA, Stevens DP, Cook N, Soil testing for heavy metals. Communications in Soil Science and Plant Analysis 2000; 31(11-14): 1661-1700 https://doi.org/10.1080/00103620009370531

McLaughlin MJ, Hamon RE, McLaren RG, Speir TW, Rogers SL. A bioavailability-based rationale for controlling metal and metalloid contamination of agricultural land in Australia and New Zealand. Soil Research 2000; 38(6): 1037-1086 http://dx.doi.org/10.1071/SR99128

Karalic K, Loncaric Z, Popovic B, Zebec V, Kerovec D. Liming effect on soil heavy metals availability. Poljoprivreda 2013; 19(1): 59-64.

Parecido RJ, Soratto RP, Perdona MJ, Gitari HI, Dognani V, Santos AR, Silveira L. Liming Method and Rate Effects on Soil Acidity and Arabica Coffee Nutrition, Growth, and Yield. Journal of Soil Science and Plant Nutrition, 2021; 21: 2613–2625 https://doi.org/10.1007/s42729-021-00550-9

Boyd CE. Use of agricultural limestone and lime in aquaculture. CAB Reviews 2017; 12 (015): 1-10 http://dx.doi.org/10.1079/PAVSNNR201712015

Cifu M, Qinglin F. Changes in chemical properties of red soil after surface application of powdered limestone, Acta Pedologica Sinica 1995; 3

Haque F, Chiang YW, Santos RM. Alkaline Mineral Soil Amendment: A Climate Change ‘Stabilization Wedge’?. Energies 2019; 12(12): 2299 https://doi.org/10.3390/en12122299

Renforth P, Manning DAC, Lopez-Capel E. Carbonate precipitation in artificial soils as a sink for atmospheric carbon dioxide. Applied Geochemistry 2009; 24(9): 1757-1764 http://dx.doi.org/10.1016/j.apgeochem.2009.05.005

[12] Milic S. Soil Fertility on Privately Owned Lands in Various Agricultural Production Regions of Vojvodina, In: Proceedings of 45th Symposium on Agriculture, Zlatibor, Serbia, 2001; Available online: www.nsseme.com /about /inc /SAS /45SAS/2011-02-04/3%Milic.pdf

Silva AC, Silva EMS, de Barros MR, Marinho DY. Limestone fines reuse for agriculture through briquetting, Tecnologiaem Metalurgia, Materiais e Mineração 2016; 13(4): 365-372 http://dx.doi.org/10.4322/2176-1523.1147

Brožek M, Study of briquette properties at their long-timestorage. J. For. Sci. 2013; 59(3): 101-106. https://doi.org/10.17221/27/2012-JFS

Yun SW, Yu C. Immobilization of Cd, Zn, and Pb from Soil Treated by Limestone with Variation of pH Using a Column Test, Journal of Chemistry 2015; 2015: Article ID 641415, 8 pages, https://doi.org/10.1155/2015/641415

Lim JM, You Y, Kamala-Kannan S, Oh SG. Oh B-T. Stabilization of Metals-contaminated Farmland Soil using Limestone and Steel Refining Slag, J. Soil Groundw. Environ. 2014; 19 (5): 1~8. DOI: http://dx.doi.org/10.7857/JSGE.2014.19.5.001

Sekulic Ž, Mihajlovic S, Kašic V, Cosic V, Liming Acid Soils Using Lithothamnium Limestone. In: Proceedings of Natural Mineral Resources and the Possibility of their Use in Agriculture and Food Industry, Belgrade, Serbia, 2006, pp. 113-123.

Silva CA, Barros MR, Silva MSE, Marinho YD, Lopes FD, Sousa ND, Tomaz SR. Limestone briquette Production and Characterization. Inter. Journal of Environmental, Chemical, Ecological, Geological and Geophysical Engineering. 2016; 10 (10): 1006-1012.

Siddique IA, Mahmud AA, Hossain M, Islam MR, Gaihre YK, Singh U. Movement and Retention of NH4-N in Wetland Rice Soils as Affected by Urea Application Methods. Journal of Soil Science and Plant Nutrition, 2020; 20 (2):589-597. http://dx.doi.org/10.1007/s42729-019-00148-2

Cabiscol R, Shi H, Wünsch I, Magnanimo V, Finke JH, Luding S, Kwade A. Effect of particle size on powder compaction and tablet strength using limestone, Advanced Powder Technology, 2020;31 (3):1280-1289. http://dx.doi.org/10.1016/j.apt.2019.12.033

Pietsch W. Agglomeration Processes – Phenomena, Technologies, Equipment; Wiley-VCH Verlag GmbH: Weinheim, Germany, 2001.

Zhou HY, Zhou JM, Peng HY, Deng SX. Experiment Study of Preparation Process of Limestone-Upright-Furnace Briquette, Coal Technology 2005; 12.

Jovanovic VD, Kneževic DN; Sekulic ŽT, Kragovic MM, Stojanovic JN, Mihajlovic SR, Nišic DD, Radulovic DS, Ivoševic BB, Petrov MM. Effects of bentonite binder dosage on the properties of green limestone pellets. Chem. Ind. 2016; 10: 135-144 http://dx.doi.org/10.2298/HEMIND160210023J

Gluba T. The Effect of Wetting Conditions on the Strength of Granules. Physicochem. Probl. Miner. Process.2006; 36(1): 233-242.

Sastry KVS, Fuerstenau DW. Kinetics of Green Pellet Growth by the Layering Mechanism. Transactions of AIME. 1977; 262: 43–47.

Nicol SK, Adamiak ZP. Role of Bentonite in Wet Pelletizing Processes. Trans. IMM. 1973; 82: C26-C33.

M. Petrovic, Mineral Processing – Fundamentals of Agglomeration, PhD dissertation Faculty of Mining, Geology and Civil Engineering: Tuzla, Bosnia and Herzegovina; (2008) p. 288.

Waters PL. Briquette Binders, A Reappraisal, In: Proceedings of the 12th Biennial Conference of the Institute for Briquetting Agglomeration, Institute for Briquetting and Agglomeration, Vancouver, Canada, 1971, pp. 145-159.

Albert KB, Langford D. Pelletizing Limestone Fines, Mars Mineral, Pennsylvania. 1998; pp. 12-29.

Orolínová Z, Mockovciaková A, Dolinská S, Briancin J, Effect of thermal treatment on the Bentonite properties. Arhiv za tehnicke nauke. 2012; 7(1): 49-56. http://dx.doi.org/10.5825/afts.2012.0407.049O

Brunerova A, Ivanova A, Brozek M, Mechanical durability of digestate briquettes mixed with mineral additives. In: Proceedings Engineering for rural development. Jelgava, Latvia, 2016, pp. 971-976.

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