Razvoj i karakterizacija elektrohemijskog senzora na bazi ugljenika modifikovanog nanočesticama TiO2 Naučni rad
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Cilj ove studije je razvoj i karakterizacija elektrohemijskog senzora na bazi ugljenika, modifikovanog nanočesticama TiO2 za potencijalnu primjenu u elektroanalitičkim tehnikama. Vršena su ispitivanja uticaja udjela vezivnog sredstva i modifikatora na morfološke, fizičko-hemijske i elektrohemijske karakteristike elektrodnog materijala radi određivanja optimalnog odnosa ugljenični materijal/vezivo/modifikator. Ugljenične paste su pripremljene od grafitnog praha modifikovanog nanočesticama TiO2 i tečnih ugljovodonika. Skenirajuća elektronska mikroskopija pokazala je da elektrodni materijal postaje kompaktniji sa dodatkom vezivnog materijala i povećanjem njegovog udjela, te da nema značajnih morfoloških razlika s porastom udjela nanočestica TiO2 koje su prilično homogeno raspodjeljene u grafitnom elektrodnom materijalu. Rezultati ispitivanja ukazuju da modifikovanu ugljeničnu pastu sa sadržajem 40 vol.% parafinskog ulja (PU) i 6-8 mas.% nanočestica TiO2 karakteriše najmanja vrijednost specifičnog otpora. Primjenom ciklične voltametrije dobijen je najizraženiji stepen reverzibilnosti u odnosu na standardni reverzibilni redoks sistem ([Fe(CN)]3-/4-) kod elektrodnog materijala sa sadržajem 30–40 vol.% PU i 8-10 mas.% nanočestica TiO2. Karakterizacijom elektrodnog materijala na bazi ugljenika modifikovanih nanočesticama TiO2 utvrđeno je da optimalan sastav sadrži 40 vol.% PU i 6-8 mas.% nanočestica TiO2, što je od važnosti za primjenu u elektroanalitičkim tehnikama.
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