Study of microstructural and thermal properties of the Sn-Bi alloys Original scientific paper

Main Article Content

Kristina Božinović
https://orcid.org/0000-0002-9834-448X
Dragan Manasijević
https://orcid.org/0000-0002-7828-8994
Ljubiša Balanović
https://orcid.org/0000-0002-3551-6731
Milan Gorgievski
https://orcid.org/0000-0002-9899-719X
Uroš Stamenković
https://orcid.org/0000-0002-7579-2159
Miljan Marković
https://orcid.org/0000-0002-4734-1481
Zoran Mladenović
https://orcid.org/0000-0001-5393-0314

Abstract

Lead-free solders have become a main focus of the electronic industry in recent years, because of the high toxicity of lead. Alloys based on the Sn-Bi system figure as potential replacements for Sn-Pb alloys in soldering due to favorable properties and low cost. One of the main advantages of these alloys are low melting temperatures, while additional advantages include good compatibility with substrates, low process temperature, high reliability, and potential applications in conjunction with reduced graphene oxide nanosheets as thermal interface materials. In this paper, characterization of microstructural and thermal properties as well as hardness measurements of seven alloys of different Sn-Bi compositions are performed. Structural properties of the samples were analyzed using optical microscopy and scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM-EDS). Thermal conductivity of the samples was investigated using the xenon-flash method, and phase transition temperatures were measured using the differential scanning calorimetry (DSC) analysis.

Article Details

Section

Engineering of Materials - Metal materials

How to Cite

[1]
K. Božinović, “Study of microstructural and thermal properties of the Sn-Bi alloys: Original scientific paper”, Hem Ind, vol. 75, no. 4, pp. 227–239, Sep. 2021, doi: 10.2298/HEMIND210119021B.

References

Frongia F, Pilloni M, Scano A, Ardu A, Cannas C, Musinu A, Borzone G, Delsante S, Novakovic R, Ennas G, Ennas. Synthesis and melting behaviour of Bi, Sn and Sn–Bi nanostructured alloy. J. Alloys Compd. 2015; 623: 7-14. https://doi.org/10.1016/j.jallcom.2014.08.122

Ren G, Wilding I, Collins M. Alloying influences on low melt temperature SnZn and SnBi solder alloys for electronic interconnections. J. Alloys Compd. 2016; 665: 251-260. https://doi.org/10.1016/j.jallcom.2016.01.006

Zhang X. P, Yu C. B, Zhang Y. P, Shrestha S, Dorn L. Processing treatment of a lead-free Sn–Ag–Cu–Bi solder by rapid laser-beam reflowing and the creep property of its soldered connection. J. Mater. Process. Technol. 2007; 192: 539-542. https://doi.org/10.1016/j.jmatprotec.2007.04.072

Kanlayasiri K, Ariga T. Physical properties of Sn58Bi–xNi lead-free solder and its interfacial reaction with copper substrate. Mater. Des. 2015; 86: 371-378. https://doi.org/10.1016/j.matdes.2015.07.108

Sun H, Li Q, Chan Y. A study of Ag additive methods by comparing mechanical properties between Sn57. 6Bi0. 4Ag and 0.4 wt% nano-Ag-doped Sn58Bi BGA solder joints. J. Mater. Sci.: Mater. Electron. 2014; 25: 4380-4390. https://doi.org/10.1007/s10854-014-2177-7

Silva B, Garcia A, Spinelli J. Complex eutectic growth and Bi precipitation in ternary Sn-Bi-Cu and Sn-Bi-Ag alloys. J. Alloys Compd. 2017; 691: 600-605. https://doi.org/10.1016/j.jallcom.2016.09.003

Abtew M, Selvaduray G. Lead-Free Solders in Microelectronics. Mater. Sci. Eng. 2000; 27: 95-141. https://doi.org/10.1016/S0927-796X(00)00010-3

Braga M. H, Vizdal J, Kroupa A, Ferreira J, Soares D, Malheiros L. F. The experimental study of the Bi–Sn, Bi–Zn and Bi–Sn–Zn systems. Calphad. 2007; 31: 468–478. https://doi.org/10.1016/j.calphad.2007.04.004

Mokhtari O, Nishikawa H. Correlation between microstructure and mechanical properties of Sn–Bi–X solders. Mater. Sci. Eng. 2016; 651: 831-839. https://doi.org/10.1016/j.msea.2015.11.038

Zhao J, Qi L, Wang X, Wang L. Influence of Bi on microstructures evolution and mechanical properties in Sn–Ag–Cu lead-free solder. J. Alloys Compd. 2004; 375: 196-201. https://doi.org/10.1016/j.jallcom.2003.12.005

Li J, Mannan S, Clode M, Whalley D, Hutt D. Interfacial reactions between molten Sn–Bi–X solders and Cu substrates for liquid solder interconnects. Acta Mater. 2006; 54: 2907-2922. https://doi.org/10.1016/j.actamat.2006.02.030

Shen J, Pu Y, Yin H, Luo D, Chen J. Effects of minor Cu and Zn additions on the thermal, microstructure and tensile properties of Sn–Bi-based solder alloys. J. Alloys Compd. 2014; 614: 63-70. https://doi.org/10.1016/j.jallcom.2014.06.015

Shalaby R. Effect of silver and indium addition on mechanical properties and indentation creep behavior of rapidly solidified Bi–Sn based lead-free solder alloys. Mater. Sci. Eng., A. 2013; 560: 86-95. https://doi.org/10.1016/j.msea.2012.09.038

Miao H, Duh J. Microstructure evolution in Sn–Bi and Sn–Bi–Cu solder joints under thermal aging. Mater. Chem. Phys.. 2013; 71: 255-271. https://doi.org/10.1016/S0254-0584(01)00298-X

Peng Y, Deng K. Fabrication of reduced graphene oxide nanosheets reinforced Sn–Bi nanocomposites by electro-chemical deposition. Compos. Part A Appl. Sci. Manuf. 2015; 73: 55–62. https://doi.org/10.1016/j.compositesa.2015.03.006

Billah M, Chen Q. Thermal conductivity of Ni-coated MWCNT reinforced 70Sn-30Bi alloy. Compos. B. Eng. 2017; 129: 162-168. https://doi.org/10.1016/j.compositesb.2017.07.071

Wang J, Wei H, He P, Lin T, Lu F. Microstructure and mechanical properties of tin-bismuth solder reinforced by aluminum borate whiskers. J. Electron. Mater. 2015; 44: 3872-3879. https://doi.org/10.1007/s11664-015-3896-0

Peng Y, Deng K. Study on the mechanical properties of the novel Sn–Bi/Graphene nanocomposite by finite element simulation. J. Alloys Compd. 2015; 625: 44-51. https://doi.org/10.1016/j.jallcom.2014.11.110

Lai Z, Ye D. Microstructure and fracture behavior of non eutectic Sn–Bi solder alloys. J. Mater. Sci.: Mater. Electron.2016; 27: 3182-3192. https://doi.org/10.1007/s10854-015-4143-4

Silva B, Reinhart G, Nguyen-Thi H, Mangelinck-Noël N, Garcia A, Spinelli J. Microstructural development and mechanical properties of a near-eutectic directionally solidified Sn–Bi solder alloy. Mater. Charact. 2015; 107: 43-53. https://doi.org/10.1016/j.matchar.2015.06.026

Gao L, Wang J, Lin T, He P, Lu F. Improvement of microstructure and mechanical properties of Sn-58Bi alloy with La2O3. In: 14th International Conference on Electronic Packaging Technology. Dalian, China, 2013, pp. 193-195.

Osório W, Peixoto L, Garcia L, Mangelinck-Noël N, Garcia A. Microstructure and mechanical properties of Sn–Bi, Sn–Ag and Sn–Zn lead-free solder alloys. J. Alloys Compd. 2013; 572: 97-106. https://doi.org/10.1016/j.jallcom.2013.03.234

Guo Q, Zhao Z, Shen C. Comparison study on microstructure and mechanical properties of Sn-10Bi and Sn-Ag-Cu solder alloys and joints. Microelectron Reliab. 2017; 78: 72-79.

Wang Q, Cheng X, Li Y, Yu G, Liu Z. Microstructures and Thermal Properties of Sn–Bi–Zn–Ga Alloys as Heat Transfer and Heat Storage Materials. J. Wuhan Univ. Technol. Mater. Sci. Ed. 2019; 34: 676-683. https://doi.org/10.1007/s11595-019-2103-1

Wang F, Huang Y, ZhangZ, Yan C. Interfacial reaction and mechanical properties of Sn-Bi solder joints. Mater. 2017; 10: 920-936. https://doi.org/10.3390/ma10080920

Hua F, Zequn M, Glazer J. Eutectic Sn-Bi as an alternative to Pb-free solders. In: Proceedings of 48th Electronic Components and Technology Conference. Seattle, Washington, 1998, pp. 277-283.

Dong W, Shi Y, Xia Z, Lei Y, Guo F. Effects of trace amounts of rare earth additions on microstructure and properties of Sn-Bi-based solder alloy. J. Electron. Mater. 2008; 37: 982-991. https://doi.org/10.1007/s11664-008-0458-8

Morando C, Fornaro O, Garbellini O, Palacio H. Thermal properties of Sn-based solder alloys. J. Mater. Sci.: Mater. Electron. 2014; 25: 3440-3447. https://doi.org/10.1007/s10854-014-2036-6

Hu X, Li Y, Min Z. Interfacial reaction and growth behavior of IMCs layer between Sn–58Bi solders and a Cu substrate. J. Mater. Sci.: Mater. Electron. 2013; 24: 2027-2034 https://doi.org/10.1007/s10854-012-1052-7

Manasijević D, Balanović Lj, Ćosović V, Minić D, Premović M, Gorgievski M, Stamenković U, Talijan N. Thermal characterization of the In–Sn–Zn eutectic alloy. Metall. Mater. Eng. 2019; 25: 325-334. https://doi.org/10.30544/456

Marković B, Živković D, Manasijević D, Talijan N, Sokić M, Ćosović V. Phase Equilibria Calculation and Investigation of Hardness and Electrical Conductivity for Alloys in Selected Sections of Bi-Cu-Ni System. J. powder metall. min. 2012; 2:104 https://doi.org/10.4172/2168-9806.1000104

Kroupa A, Dinsdale A, Watson A, Vrestal J, Vízdal J, Zemanova A. The development of the COST 531 lead-free solders thermodynamic database. JOM. 2007; 59: 20-25. https://doi.org/10.1007/s11837-007-0084-6

Cao W, Chen S, Zhang F, Wu K, Yang Y, Chang Y, Schmid-Fetzer R, Oates W. PANDAT Software with PanEngine, PanOptimizer and PanPrecipitation for Multi-Component Phase Diagram Calculation and Materials Property Simulation. Calphad. 2009; 33: 328–342. https://doi.org/10.1016/j.calphad.2008.08.004

Vízdal J, Braga M, Kroupa A, Richter K, Soares D, Malheiros L, Ferreira J. Thermodynamic assessment of the Bi–Sn–Zn System. Calphad. 2007; 31: 438-448. https://doi.org/10.1016/j.calphad.2007.05.002

Parker W, Jenkins R, Butler C, Abbot G. Flash Method of Determining Thermal Diffusivity, Heat Capacity, and Thermal Conductivity. J. Appl. Phys. 1961; 32: 1679-84. https://doi.org/10.1063/1.1728417

Engineering ToolBox, (2005). Thermal Conductivity of Metals, Metallic Elements and Alloys. [online] Available at: https://www.engineeringtoolbox.com/thermal-conductivity-metals-d_858.html. Accessed January 11, 2021.

Indium Corp. Indalloy® 281 Bi-Sn Solder Alloy. http://www.matweb.com/search/datasheet.aspx?matguid=967a4cd7871b46fa9128a29c303cf8be. Accessed January 11, 2021.

ASM Handbook Volume 2. Properties and Selection: Nonferrous Alloys and Special-Purpose Materials. ASM International; 1990.

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