Analysis of thermophysical properties of binary systems containing ethyl acetate and 1-propanol or 1-butanol
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Abstract
The aim of this research is the experimental determination of density, viscosity, refractive index and speed of sound for binary mixtures of the ester ethyl acetate and alcohols. Experimental measurements were carried out for two systems with 1-propanol and 1-butanol at atmospheric pressure and in a temperature range 288.15 - 323.15 K. Results of experimental measurements were further used to determine excess molar volumes, viscosity deviations, refractive index deviations, and excess isentropic compressibility for each investigated mixture. These calculated data were correlated using the empirical Redlich-Kister equation. Positive values of the excess molar volume and isentropic compressibility appear for both analysed systems, while values of viscosity and refractive index deviations are negative. The structure and specific characteristics of different molecules in considered mixtures and determined non-ideal behaviour allow the insight into the possible type of interactions in the mixture, interstitial accommodation and structural effects.
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Hendriks E, Kontogeorgis GM, Dohrn R, de Hemptinne J-C, Economou IG, Žilnik LjF, Vesovic V. Industrial Requirements for Thermodynamics and Transport Properties. Ind Eng Chem Res. 2010; 49: 11131-11141.
Bajić DM, Živković EM, Šerbanović SP, Kijevčanin MLj. Volumetric and Viscometric Study of Binary Systems of Ethyl Butyrate with Alcohols. J Chem Eng Data. 2014; 59: 3677−3690.
Majstorović DM, Živković EM, Mitrović AD, Munćan JS, Kijevčanin MLj. Volumetric and viscometric study with FT-IR analysis of binary systems with diethyl succinate and alcohols. J Chem Thermodyn. 2016; 101: 323–336.
Majstorović DM, Živković EM, Kijevčanin MLj. Volumetric and viscometric study and modelling of binary systems of diethyl tartrate and alcohols. J Mol Liq. 2017; 248: 219–226.
Khire S, Bhagwat PV, Fernandes M, Gangundi PB, Vadalia H. Esterification of lower aliphatic alcohols with acetic acid in presence of different acid catalysts. Indian J Chem Technol. 2012; 19: 342-350.
Oswal SL, Oswal P, Modi PS, Dave JP, Gardas RL. Acoustic, volumetric, compressibility and refractivity properties and Florys reduction parameters of some homologous series of alkyl alkanoates from 298.15 to 333.15 K. Thermochim Acta. 2004; 410: 1-14.
Wang Y, Gao H, Yan W. Excess molar enthalpies of diethyl malonate+ (1-butanol, 2-methyl-1-propanol, 1-pentanol, n-heptane, and ethyl acetate) at T = (288.2, 298.2, 313.2, 328.2, 338.2, and 348.2 K) and p = 101.3 kPa. Fluid Phase Equilib. 2010; 291: 8-12.
Djojoputro H, Ismadji S. Density and Viscosity Correlation for Several Common Fragrance and Flavor Esters. J Chem Eng Data. 2005; 50: 727-731.
Gardas RL, Johnson I, Vaz DMD, Fonseca IMA, Ferreira AGM. PVT Property Measurements for Some Aliphatic Esters from (298 to 393) K and up to 35 MPa. J Chem Eng Data. 2007; 52: 737 -751.
Vercher E, Llopis FJ, González-Alfaro MV, Martínez-Andreu A. Density, Speed of Sound, and Refractive Index of 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate with Acetone, Methyl Acetate, and Ethyl Acetate at Temperatures from (278.15 to 328.15) K. J Chem Eng Data. 2010; 55: 1377-1388.
Zhang G, Hayduk W. The Solubilitv of Isobutane and Isobutylene in Associated Solvents. Can J Chem Eng. 1984; 62: 713-718.
Abraham T, Bery V, Kudchadker AP. Densities of some organic substances. J Chem Eng Data. 1971; 16: 355-356.
Sakurai M, Nakamura K, Nitta K. Partial Molar Volumes of Alkyl Acetates in Water. J Chem Eng Data. 1996; 41: 1171-1175.
Fernández L, Pérez E, Ortega J, Canosa J, Wisniak J. Measurements of the Excess Properties and Vapor-Liquid Equilibria at 101.32 kPa for Mixtures of Ethyl Ethanoate + Alkanes (from C5 to C10). J Chem Eng Data. 2010; 55: 5519-5533.
Resa JM, González C, Goenaga JM, Iglesias M. Temperature Dependence of Excess Molar Volumes of Ethanol + Water + Ethyl Acetate. J Solution Chem. 2004; 33: 169-198.
Tovar CA, Carballo E, Cerdeiriña CA, Romaní L. Excess Molar Volumes and Excess Molar heat Capacities of Mixtures Containing (Mono and Poly)ethers + Ethyl Acetate. J Chem Eng Data. 1997; 42: 1085-1089.
de Almeida BF, Waldrigui TM, Alves TC, de Oliveira LH, Aznar M. Experimental and calculated liquid-liquid equilibrium data for water + furfural + solvents. Fluid Phase Equilib. 2012; 334: 97-105.
Malek NI, Singh A, Surati R, Ijardar SP. Study on thermo physical and excess molar properties of binary systems of ionic liquids. I: [Cnmim][PF6] (n = 6, 8) and alkyl acetates. J Chem Thermodyn. 2014; 74: 103-118.
López-Lázaro JS, Iglesias-Silva GA, Estrada-Baltazar A, Barajas-Fernández J. Density and Surface Tension of Binary Mixtures of 2,2,4-Trimethylpentane + n-Heptane, 2,2,4-Trimethylpentane + n-Octane, Ethyl Acetate + Benzene, and Butanenitrile + Benzene from (293.15 to 323.15) K. J Chem Eng Data. 2015; 60: 1823-1834.
Oswal SL, Putta S.S.R. Excess molar volumes of binary mixtures of alkanols with ethyl acetate from 298.15 to 323.15 K. Thermochim Acta. 2001; 373: 141-152.
Pal A, Kumar H. Excess molar volumes, and viscosities of tetraethylene glycol dimethyl ether with methyl acetate, ethyl acetate, and propyl acetate at (298.15, 308.15, and 318.15) K. J Mol Liq. 2000; 89: 189-206.
Aminabhavi TM, Phayde HTS, Khinnavar RS, Gopalakrishna B, Hansen KC. Densities, refractive indices, speeds of sound, and shear viscosities of diethylene glycol dimethyl ether with ethyl acetate, methyl benzoate, ethyl benzoate, and diethyl succinate in the temperature range from 298.15 to 318.15 K. J Chem Eng Data. 1994; 39: 251-260.
Lee S-L, Tu C-H. Densities and Viscosities of Four Alkyl Esters with Nitromethane Systems at (293.15, 303.15, and 313.15) K. J Chem Eng Data. 1999; 44: 108-111.
Modarress H, Mohsen-Nia M. Experimental and theoretical studies of viscosities of ternary mixture [2-propanol+ethyl acetate+n-hexane] and its binary constituents at 298.15, 308.15 and 313.15K. Phys Chem Liq. 2006; 44: 67-76.
Kumar DBK, Reddy KR, Rao GS, Sandhyasri PB, Begum Z, Rambabu C. Measurements of some physical properties of binary liquid mixtures (N-methyl-2-pyrrolidone + an aliphatic ester) at several temperatures and data processing of viscosity and ultrasonic speed. J Mol Liq. 2013; 183: 31-44.
Aminabhavi TM, Banerjee K. Density, Viscosity, Refractive Index, and Speed of Sound in Binary Mixtures of Acrylonitrile with Methyl Acetate, Ethyl Acetate, n-Propyl Acetate, n-Butyl Acetate, and 3-Methylbutyl-2-acetate in the Temperature Interval (298.15-308.15) K. J Chem Eng Data. 1998; 43: 514-518.
Aralaguppi MI, Jadar CV, Aminabhavi TM. Density, Viscosity, Refractive Index, and Speed of Sound in Binary Mixtures of 2-Chloroethanol with Methyl Acetate, Ethyl Acetate, n-Propyl Acetate, and n-Butyl Acetate. J Chem Eng Data. 1999; 44: 441-445.
Sastry NV, Patel MC. Densities, Excess Molar Volumes, Viscosities, Speeds of Sound, Excess Isentropic Compressibilities, and Relative Permittivities for Alkyl (Methyl, Ethyl, Butyl, and Isoamyl) Acetates + Glycols at Different Temperatures. J Chem Eng Data. 2003; 48: 1019-1027.
González B, Domínguez A, Tojo J. Dynamic Viscosities, Densities, and Speed of Sound and Derived Properties of the Binary Systems Acetic Acid with Water, Methanol, Ethanol, Ethyl Acetate and Methyl Acetate at T = (293.15, 298.15, and 303.15) K at Atmospheric Pressure. J Chem Eng Data. 2004; 49: 1590-1596.
Wankhede NN, Wankhede DS, Lande MK, Arbad BR. Molecular interactions in (2,4,6-trimethyl-1,3,5-trioxane + n-alkyl acetates) at T = (298.15, 303.15, and 308.15) K. J Chem Thermodyn. 2006; 38: 1664-1668.
Patwari MK, Bachu RK, Boodida S, Nallani S. Densities, Viscosities, and Speeds of Sound of Binary Liquid Mixtures of Sulfolane with Ethyl Acetate, n-Propyl Acetate, and n-Butyl Acetate at Temperature of (303.15, 308.15, and 313.15) K. J Chem Eng Data. 2009; 54: 1069-1072.
Syeda AB, Bachu RK, Koppula AJ, Boodida S, Nallani S. Volumetric and Transport Properties of Binary Liquid Mixtures of Phenylacetonitrile with Aliphatic Esters at Temperatures of (303.15 to 313.15) K. J Chem Eng Data. 2010; 55: 1067-1071.
Ortega J, Bolat G, Marrero E. Thermodynamic study of the mixtures (butylbenzene + an alkane or + an alkyl ethanoate): experimental HmE and VmE values. Phys Chem Liq. 2007; 45: 251-259.
Aminabhavi TM, Raikar SK, Balundgi RH. Densities, viscosities, refractive indices, and speeds of sound in methyl acetoacetate + methyl acetate, + ethyl acetate, + n-butyl acetate, + methyl benzoate, and + ethyl benzoate at 298.15, 303.15, and 308.15 K. J Chem Eng Data. 1993; 38: 441-445.
Baragi JG, Aralaguppi MI, Aminabhavi TM, Kariduraganavar MY, Kulkarni SS. Density, Viscosity, Refractive Index, and Speed of Sound for Binary Mixtures of 1,4-Dioxane with Different Organic Liquids at (298.15, 303.15, and 308.15) K. J Chem Eng Data. 2005; 50: 917-923.
Pereiro AB, Rodríguez A. Thermodynamic Properties of Ionic Liquids in Organic Solvents from (293.15 to 303.15) K. J Chem Eng Data. 2007; 52: 600-608.
Pereiro AB, Rodríguez A. Mixing properties of binary mixtures presenting azeotropes at several temperatures. J Chem Thermodyn. 2007; 39: 1219-1230.
Resa JM, González C, Goenaga JM, Iglesias M. Influence of temperature on ultrasonic velocity measurements of ethanol+water+ethyl acetate mixtures. Phys Chem Liq. 2005; 43: 65-89.
Pal A, Kumar H, Maan R, Sharma HK. Densities and Speeds of Sound of Binary Liquid Mixtures of Some n-Alkoxypropanols with Methyl Acetate, Ethyl Acetate, and n-Butyl Acetate at T = (288.15, 293.15, 298.15, 303.15, and 308.15) K. J Chem Eng Data. 2013; 58: 225-239.
Pal A, Kumar H, Maan R, Sharma HK. Volumetric and Acoustic Studies of Binary Liquid Mixtures of Dipropylene Glycol Dimethyl Ether with Methyl Acetate, Ethyl Acetate and n-Butyl Acetate in the Temperature Range T = (288.15, 293.15, 298.15, 303.15, and 308.15) K. J Solution Chem. 2013; 42: 1988-2011.
Nallani S, Boodida S, Tangeda SJ. Density and Speed of Sound of Binary Mixtures of N-Methylacetamide with Ethyl Acetate, Ethyl Chloroacetate, and Ethyl Cyanoacetate in the Temperature Interval (303.15 to 318.15) K. J Chem Eng Data. 2007; 52: 405-409.
Bahadur I, Deenadayalu N. Apparent molar volume and apparent molar isentropic compressibility for the binary systems {methyltrioctylammoniumbis (trifluoromethylsulfonyl)imide + ethyl acetate or ethanol} at different temperatures under atmospheric pressure. Thermochim Acta. 2013; 566: 77-83.
Sastry NV, Patel SR, Soni SS. Excess molar volumes, excess isentropic compressibilities, excess viscosities, relative permittivity and molar polarization deviations for methyl acetate+, ethyl acetate+, butyl acetate+, isoamyl acetate+, methyl propionate+, ethyl propionate+, ethyl butyrate+, methyl methacrylate+, ethyl methacrylate+, and butyl methacrylate + cyclohexane at T = 298.15 and 303.15 K. J Mol Liq. 2013; 183: 102-112.
Dávila MJ, Alcalde R, Atilhan M, Aparicio S. PρT measurements and derived properties of liquid 1-alkanols. J Chem Thermodyn. 2012; 47: 241-259.
Kretschmer CB. The thermal expansion of water and 1-propanol. J Phys Chem. 1951; 55: 1351-1355.
Yang C, Lai H, Liu Z, Ma P. Density and Viscosity of Binary Mixtures of Diethyl Carbonate with Alcohols at (293.15 to 363.15) K and Predictive Results by UNIFAC-VISCO Group Contribution Method. J Chem Eng Data. 2006; 51: 1345-1351.
Diaz Peña M, Tardajos G. Isothermal Compressibilities of n-1-Alcohols from Methanol to 1-Dodecanol at 298.15, 308.15, 318.15, and 333.15 K. J Chem Thermodyn. 1979; 11: 441-445.
Ling TD, Van Winkle M. Properties of binary mixtures as a function of composition. Ind Eng Chem Chem Eng Data Ser. 1958; 3: 88-95.
Kumagai A, Yokoyama C. Liquid Viscosity of Binary Mixtures of Methanol with Ethanol and 1-Propanol from 273.15 to 333.15 K. Int J Thermophys. 1998; 19: 3-13.
Valtz A, Teodorescu M, Wichterle I, Richon D. Liquid densities and excess molar volumes for water + diethylene glycolamine, and water, methanol, ethanol, 1-propanol + triethylene glycol binary systems at atmospheric pressure and temperatures in the range of 283.15-363.15 K. Fluid Phase Equilib. 2004; 215: 129-142.
Watson G, Lafitte T, Zéberg-Mikkelsen CK, Baylaucq A, Bessieres D, Boned C. Volumetric and derivative properties under pressure for the system 1-propanol + toluene: A discussion of PC-SAFT and SAFT-VR. Fluid Phase Equilib. 2006; 247: 121-134.
Vercher E, Orchillés AV, Miguel PJ, Martínez-Andreu A. Volumetric and Ultrasonic Studies of 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate Ionic Liquid with Methanol, Ethanol, 1-Propanol, and Water at Several Temperatures. J Chem Eng Data. 2007; 52: 1468-1482.
Alaoui FEM, Montero EA, Bazile J-P, Aguilar F, Boned C. (p, VE, T) Measurements of mixtures (DBE + alcohol) at temperatures from (293.15 to 353.15) K and at pressures up to 140 MPa. Fluid Phase Equilib. 2014; 363: 131-148.
Coquelet C, Valtz A, Richon D, de la Funete JC. Volumetric properties of the boldine + alcohol mixtures at atmospheric pressure from 283.15 to 333.15K. A new method for the determination of the density of pure boldine. Fluid Phase Equilib. 2007; 259: 33-38.
Huo Y, Xia S, Ma P. Densities of Ionic Liquids, 1-Butyl-3-methylimidazolium Hexafluorophosphate and 1-Butyl-3-methylimidazolium Tetrafluoroborate, with Benzene, Acetonitrile, and 1-Propanol at T = (293.15 to 343.15) K. J Chem Eng Data. 2007; 52: 2077-2082.
Zarei HA, Jalili F. Densities and derived thermodynamic properties of (2-methoxyethanol + 1-propanol, or 2-propanol, or 1,2-propandiol) at temperatures from T = (293.15 to 343.15) K. J Chem Thermodyn. 2007; 39: 55-66.
Zarei HA, Asadi S, Iloukhani H. Temperature dependence of the volumetric properties of binary mixtures of (1-propanol, 2-propanol and 1,2-propanediol) at ambient pressure (81.5 kPa). J Mol Liq. 2008; 141: 25-30.
Baylaucq A, Watson G, Zéberg-Mikkelsen C, Bazile J-P, Boned C. Dynamic Viscosity of the Binary System 1-Propanol + Toluene as a Function of Temperature and Pressure. J Chem Eng Data. 2009; 54: 2715-2721.
Assael MJ, Polimatidou SK. Measurements of the viscosity of alcohols in the temperature range 290-340 K at pressures up to 30 MPa. Int J Thermophys. 1994; 15: 95-107.
Domańska U, Laskowska M. Temperature and Composition Dependence of the Density and Viscosity of Binary Mixtures of {1-Butyl-3-methylimidazolium Thiocyanate + 1-Alcohols}. J Chem Eng Data. 2009; 54: 2113-2119.
Tanaka Y, Matsuda Y, Fujiwara H, Kubota H, Makita T. Viscosity of (water + alcohol) mixtures under high pressure. Int J Thermophys. 1987; 8: 147-163.
Pang F-M, Seng C-E, Teng T-T, Ibrahim MH. Densities and viscosities of aqueous solutions of 1-propanol and 2-propanol at temperatures from 293.15 K to 333.15 K. J Mol Liq. 2007; 136: 71-78.
Yan J-H, Dai L-Y, Wang X-Z, Chen Y-Q. Densities and Viscosities of Binary Mixtures of Cyclopropanecarboxylic Acid with Methanol, Ethanol, Propan-1-ol, and Butan-1-ol at Different Temperatures. J Chem Eng Data. 2009; 54: 1147-1152.
Han S, Zhu C, Ma Y. Densities and Viscosities of Naphthalen-1-ol, Naphthalen-2-ol, and 1-Aminonaphthalene in the Solvents of Ethanol, Propan-1-ol, and Butan-1-ol. J Chem Eng Data. 2012; 57: 1396-1403.
Kermanpour F, Sharifi T. Thermodynamic Study of Binary Mixture of x1 [C6mim][BF4] + x2 1-propanol: Measurements and Molecular Modeling. Thermochim Acta. 2012; 527: 211-218.
Kermanpour F, Niakan HZ, Sharifi T. Density and Viscosity Measurements of Binary Alkanol Mixtures from (293.15 to 333.15) K at Atmospheric Pressure. J Chem Eng Data. 2013; 58: 1086-1091.
Kermanpour F, Sharifi T. Measurement and Correlation of the Excess Properties of Ternary Mixture of {x1 [Hmim][BF4] + x2 1-Propanol + x3 2-Propanol} at Different Temperatures. J Chem Eng Data. 2014; 59: 1922-1929.
Normazlan WMDW, Sairi NA, Alias Y, Udaiyappan AF, Jouyban A, Khoubnasabjafari M. Composition and Temperature Dependence of Density, Surface Tension, and Viscosity of EMIM DEP/MMIM DMP + Water + 1-Propanol/2-Propanol Ternary Mixtures and Their Mathematical Representation Using the Jouyban-Acree Model. J Chem Eng Data. 2014; 59: 2337-2348.
Zhu C, Han S, Liu J, Ma Y. Densities and Viscosities of Diaminotoluene with Water, Ethanol, Propan-1-ol, and Butan-1-ol from (293.15 to 333.15) K. J Chem Eng Data. 2014; 59: 880-889.
Rauf MA, Stewart GH, Farhataziz. Viscosities and Densities of Binary Mixtures of 1-Alkanols from 15 to 55°C. J Chem Eng Data. 1983; 28: 324-328.
Garcia B, Herrera C, Leal JM. Shear viscosities of binary liquid mixtures: 2-pyrrolidone with 1- alkanols. J Chem Eng Data. 1991; 36: 269-274.
González EJ, Alonso L, Domínguez A. Physical Properties of Binary Mixtures of the Ionic Liquid 1-Methyl-3-octylimidazolium Chloride with Methanol, Ethanol, and 1-Propanol at T = (298.15, 313.15, and 328.15) K and at P = 0.1 MPa. J Chem Eng Data. 2006; 51: 1446-1452.
Ortega J. Densities and Refractive Indices of Pure Alcohols as a Function of Temperature. J Chem Eng Data. 1982; 27: 312-317.
García-Abarrio SM, Torcal M, Haya ML, Urieta JS, Mainar AM. Thermophysical properties of {(±)-linalool + propan-1-ol}: A first stage towards the development of a green process. J Chem Thermodyn. 2011; 43: 527-536.
OBrien RN, Quon D. Refractive Index of Some Alcohols and Saturated Hydrocarbons at 6328 A. J Chem Eng Data. 1968; 13: 517.
Ortega J, Matos JS, Peña JA, Paz-Andrade MI, Pias L, Fernandez J. Isobaric Expansivities of the Binary Mixtures C3H7(OH)+CnH2n+2 (n=11,12) Between 288.15 and 318.15 K. Thermochim Acta. 1988; 131: 57-64.
Aminabhavi TM, Gopalakrishna B. Densities, Viscosities, and Refractive Indices of the Binary Mixtures of Bis(2-methoxyethyl) Ether with 1-Propanol, 1-Butanol, 2-Methyl-1-propanol, and 2-Methyl-2-propanol. J Chem Eng Data. 1994; 39: 865-867.
Rodríguez A, Canosa J, Tojo J. Physical Properties of Binary Mixtures (Dimethyl Carbonate + Alcohols) at Several Temperatures. J Chem Eng Data. 2001; 46: 1476-1486.
Gupta M, Vibhu I, Shukla JP. Optical and Volumetric Study of Molecular Interactions in Binary Mixtures of Tetrahydrofuran with 1-Propanol and 2-Propanol. Phys Chem Liq. 2003; 41: 575-582.
Chen H-W, Wen C-C, Tu C-H. Excess Molar Volumes, Viscosities, and Refractive Indexes for Binary Mixtures of 1-Chlorobutane with Four Alcohols at T = (288.15, 298.15 and 308.15) K. J Chem Eng Data. 2004; 49: 347-351.
Comelli F, Francesconi R, Bigi A, Rubini K. Excess Molar Enthalpies, Molar Heat Capacities, Densities, Viscosities, and Refractive Indices of Dimethyl Sulfoxide + 1-Propanol at (288.15, 298.15, and 308.15) K and at Normal Pressure. J Chem Eng Data. 2006; 51: 1711-1716.
González EJ, González B, Macedo EA. Thermophysical Properties of the Pure Ionic Liquid 1-Butyl-1-methylpyrrolidinium Dicyanamide and Its Binary Mixtures with Alcohols. J Chem Eng Data. 2013; 58: 1440-1448.
Jiménez E, Cabanas M, Segade L, García-Garabal S, Casas H. Excess volume, changes of refractive index and surface tension of binary 1,2-ethanediol + 1-propanol or 1-butanol mixtures at several temperatures. Fluid Phase Equilib. 2001; 180: 151-164.
Fontao MJ, Iglesias M. Effect of Temperature on the Refractive Index of Aliphatic Hydroxilic Mixtures (C2-C3). Int J Thermophys. 2002; 23: 513-527.
Alfaro P, Langa E, Martínez-López JF, Urieta JS, Mainar AM. Thermophysical properties of the binary mixtures (1,8-cineole + 1-alkanol) at T = (298.15 and 313.15) K and at atmospheric pressure. J Chem Thermodyn. 2010; 42: 291-303.
Singh S, Aznar M, Deenadayalu N. Densities, speeds of sound, and refractive indices for binary mixtures of 1-butyl-3-methylimidazolium methyl sulphate ionic liquid with alcohols at T = (298.15, 303.15, 308.15, and 313.15) K. J Chem Thermodyn. 2013; 57: 238-247.
Wang M, Yin T, Xu C, Chen Z, Shen W. Liquid-Liquid Phase Equilibrium and Heat Capacity of Binary Mixture 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide + 1-Propanol. J Chem Eng Data. 2014; 59: 3389-3396.
Resa JM, González C, Goenaga JM, Iglesias M. Influence of temperature on ultrasonic velocity measurements of ethanol+water+1-propanol mixtures. J Therm Anal Calorim. 2007; 87: 237-245.
González EJ, Gonzáles B, Calvar N, Domínguez A. Physical Properties of Binary Mixtures of the Ionic Liquid 1-Ethyl-3-methylimidazolium Ethyl Sulfate with Several Alcohols at T = (298.15, 313.15, and 328.15) K and Atmospheric Pressure. J Chem Eng Data. 2007; 52: 1641-1648.
Calvar N, González EJ, Domínguez A, Macedo EA. Acoustic, volumetric and osmotic properties of binary mixtures containing the ionic liquid 1-butyl-3-methylimidazolim dicyanamide mixed with primary and secondary alcohols. J Chem Thermodyn. 2012; 50: 19-29.
González EJ, Calvar N, Domínguez A, Macedo EA. Osmotic and apparent molar properties of binary mixtures alcohol + 1-butyl-3-methylimidazolium trifluoromethanesulfonate ionic liquid. J Chem Thermodyn. 2013; 61: 64-73.
Marczak W, Dzida M, Ernst S. Determination of the thermodynamic properties of 1-propanol and 1-hexanol from speed of sound measurements under elevated pressures. High Temp - High Pressures. 2000; 32: 283-292.
Dzida M, Ernst S. Speed of Sound in Propan-1-ol + Heptane Mixtures under Elevated Pressures. J Chem Eng Data. 2003; 48: 1453-1457.
Nain AK. Ultrasonic and viscometric studies of molecular interactions in binary mixtures of formamide with ethanol, 1-propanol, 1,2-ethanediol and 1,2-propanediol at different temperatures. J Mol Liq. 2008; 140: 108-116.
Gupta M, Vibhu I, Shukla JP. Ultrasonic velocity, viscosity and excess properties of binary mixture of tetrahydrofuran with 1-propanol and 2-propanol. Fluid Phase Equilib. 2006; 244: 26-32.
Pal A, Gaba R. Densities, excess molar volumes, speeds of sound and isothermal compressibilities for {2-(2-hexyloxyethoxy)ethanol + n-alkanol} systems at temperatures between (288.15 and 308.15) K. J Chem Thermodyn. 2008; 40: 750-758.
Kumar H, Sharma S. Acoustical Studies of Binary Liquid Mixtures of Cyclopentane with 1-Alkanol at Different Temperatures and Different Approaches for Ideal Mixing Laws. J Solution Chem. 2010; 39: 967-986.
Pal A, Gaba R, Kumar H. Acoustic, Viscometric, and Spectroscopic Studies of Dipropylene Glycol Monopropyl Ether with n-Alkanols at Temperatures of 288.15, 298.15, and 308.15 K. J Solution Chem. 2011; 40: 786-802.
Dubey GP, Kaur P. Molecular interactions in binary mixtures of 1-butoxy-2-propanol with alcohols at different temperatures: A thermophysical and spectroscopic approach. J Chem Thermodyn. 2014; 79: 100-108.
Rodríguez A, Canosa J, Tojo J. Density, Refractive Index, and Speed of Sound of Binary Mixtures (Diethyl Carbonate + Alcohols) at Several Temperatures. J Chem Eng Data. 2001; 46: 1506-1515.
Hales JL, Ellender JH. Liquid Densities from 293 to 490 K of Nine Aliphatic Alcohols. J Chem Thermodyn. 1976; 8: 1177-1184.
Costello JM, Bowden ST. The Temperature Variation of Orthobaric Density Difference in Liquid-Vapor Systems. III. Alcohols. Recl Trav Chim Pays-Bas. 1958; 77: 36-46.
Safarov J, Ahmadov B, Mirzayev S, Shahverdiyev A, Hassel EP. Thermophysical properties of 1-butanol over a wide range of temperatures and pressures up to 200 MPa. J Mol Liq. 2015; 209: 465-479.
Alaoui F, Montero E, Bazile JP, Comuñas MJP, Galliero G, Boned C. Liquid density of 1-butanol at pressures up to 140 MPa and from 293.15 K to 403.15 K. Fluid Phase Equilib. 2011; 301: 131-136.
Iglesias-Silva GA, Bravo-Sánchez M, Estrada-Baltazar A, Bouchot C, Hall KR. P-ρ-T Data for 1-Butanol and Isobutyl Alcohol from (283.15 to 363.15) K at Pressures up to 66 MPa. J Chem Eng Data. 2015; 60: 1076-1090.
Valén A, López MC, Urieta JS, Royo FM, Lafuente C. Thermodynamic Study of mixtures containing oxygenated compounds. J Mol Liq. 2002; 95: 157-165.
Brunson RR, Byers CH. Viscosities of Alcohol-Hydrocarbon Systems in the Critical Region: A Dynamic Laser Light Scattering Approach, J Chem Eng Data. 1989; 34: 46-52.
Bravo-Sánchez MG, Iglesias-Silva GA, Estrada-Baltazar A, Hall KR. Densities and Viscosities of Binary Mixtures of n-Butanol with 2-Butanol, Isobutanol, and tert-Butanol from (303.15 to 343.15) K. J Chem Eng Data. 2010; 55: 2310-2315.
Domańska U, Zawadzki M, Lewandrowska A. Effect of temperature and composition on the density, viscosity, surface tension, and thermodynamic properties of binary mixtures of N-octylisoquinolinium bis{(trifluoromethyl)sulfonyl}imide with alcohols. J Chem Thermodyn. 2012; 48: 101-111.
Rodríguez M, Galán M, Muñoz MJ, Martín R. Viscosity of triglycerides + alcohols from 278 to 313 K. J Chem Eng Data. 1994; 39: 102-105.
Martínez S, Garriga R, Pérez P, Gracia M. Densities and viscosities of binary mixtures of butanone with butanol isomers at several temperatures. Fluid Phase Equilib. 2000; 168: 267-279.
Indraswati N, Mudjijati, Wicaksana F, Hindarso H. Measurements of Density and Viscosity of Binary Mixtures of Several Flavor Compounds with 1-Butanol and 1-Pentanol at 293.15K, 303.15 K, 313.15 and 323.15 K. J Chem Eng Data. 2001; 46: 696-702.
Nain AK. Refractive Indices and Deviations in Refractive Indices for Binary Mixtures of Formamide + 1-Butanol, + 2-Butanol, + 1,3-Butanediol, and + 1,4-Butanediol at Temperatures from (293.15 to 318.15) K. J Chem Eng Data. 2008; 53: 1208-1210.
de Cominges BE, Piñeiro MM, Mosteiro L, Mascato E, Mato MM, Iglesias TP, Legido JL. Temperature dependence of thermophysical properties of octane+1-butanol system. J Therm Anal Calorim. 2002; 70: 217-227.
Yu Z, Gao H, Wang H, Chen L. Densities, Excess Molar Volumes, and Refractive Properties of the Binary Mixtures of the Amino Acid Ionic Liquid [bmim][Gly] with 1-Butanol or Isopropanol at T = (298.15 to 313.15) K. J Chem Eng Data. 2011; 56: 4295-4300.
Sekhar MC, Mohan TM, Krishna TV, Venkatesulu A, Kumar KS. Density, Refractive Index, Speed of Sound and Computational Studies of Intermolecular Interactions in Binary Mixtures of 2-Chloroaniline with Butanols (1-Butanol, 2-Butanol) at T = (303.15-318.15) K. J Solution Chem. 2015; 44: 237-263.
Troncoso J, Valencia JL, Souto-Caride M, González-Salgado D, Peleteiro J. Thermodynamic Properties of dodecane + 1-butanol and + 2-butanol systems. J Chem Eng Data. 2004; 49: 1789-1793.
Valén A, Gascón I, Lafuente C, Urieta JS, Royo FM, Postigo M. Volumetric and Acoustic Properties of the Ternary Mixture 1-Butanol+1-Chlorobutane+Tetrahydrofuran at 283.15, 298.15, and 313.15 K. Int J Thermophys. 2002; 23: 1587-1598.
Vallés C, Pérez E, Cardoso M, Domínguez M, Mainar AM. Excess Enthalpy, Density, Viscosity, and Speed of Sound for the Mixture Tetrahydropyran + 1-Butanol at (283.15, 298.15, and 313.15) K. J Chem Eng Data. 2004; 49: 1460-1464.
Langa E, Mainar AM, Pardo JI, Urieta JS. Excess Enthalpy, Density, and Speed of Sound for the Mixtures β-Pinene + 1-Butanol or 2-Butanol at (283.15, 298.15, and 313.15) K. J Chem Eng Data. 2006; 51: 392-397.
Vallés C, Pérez E, Mainar AM, Santafé J, Domínguez M. Excess Enthalpy, Density, Speed of Sound, and Viscosity for 2-Methyltetrahydrofuran + 1-Butanol at (283.15, 298.15, and, 313.15) K. J Chem Eng Data. 2006; 51: 1105-1109.
Morávková L, Troncoso J, Machanová K, Sedláková Z. Volumetric behaviour of the (2,2,4-trimethylpentane + methylbenzene + butan-1-ol) ternary system and its binary sub-systems within the temperature range (298.15-328.15) K. J Chem Thermodyn. 2013; 64: 137-150.
Nain AK. Ultrasonic study of molecular interactions in binary mixtures of methyl acrylate with 1-alkanols (C4 to C10) at temperatures from (288.15 to 318.15) K. J Chem Thermodyn. 2013; 59: 49-64.
Bendiaf L, Bahadur I, Negadi A, Naidoo P, Ramjugernath D, Negadi L. Effects of alkyl group and temperature on the interactions between furfural and alcohol: Insight from density and sound velocity studies. Thermochim Acta. 2015; 599: 13-22.
Morávková L, Troncoso J, Škvorová M, Havlica J, Petrus P, Sedláková Z. Volumetric behavior of the ternary system (methyl tert-butyl ether + methylbenzene + butan-1-ol) and its binary sub-system (methyl tert-butyl ether + butan-1-ol) within the temperature range (298.15 to 328.15) K. J Chem Thermodyn. 2015; 90: 59-70.
Varfolomeev MA, Zaitseva KV, Rakipov IT, Solomonov BN, Marczak W. Speed of sound, density and related thermodynamic excess properties of binary mixtures of butan-2-one with C1-C4 n-alkanols and chloroform. J Chem Eng Data. 2014; 59: 4118-4132.
Troncoso J, Carballo E, Cerdeiriña CA, González D, Romaní L. Systematic determination of densities and speeds of sound of nitroethane + isomers of butanol in the range (283.15-308.15) K. J Chem Eng Data. 2000; 45: 594-599.
Nain AK. Molecular interactions in binary mixtures of formamide with 1-butanol, 2-butanol, 1,3-butanediol and 1,4-butanediol at different temperatures: An ultrasonic and viscometric study. Fluid Phase Equilib. 2008; 265: 46-56.
Papari MM, Ghodrati H, Fadaei F, Sadeghi R, Behrouz S, Soltani Rad MN, Moghadasi J. Volumetric and ultrasonic study of mixtures of 2-phenylethanol with 1-butanol, 2-butanol, and 2-methyl-1-butanol at T = (298.15 - 323.15) K and atmospheric pressure: Measurement and prediction. J Mol Liq. 2013; 180: 121-128.
Troncoso J, Tovar CA, Cerdeiriña CA, Carballo E, Romaní L. Temperature Dependence of Densities and Speed of Sound of Nitromethane + Butanol Isomers in the Range (288.15-308.15) K. J Chem Eng Data. 2001; 46: 312-316.
Bajić DM, Živković EM, Šerbanović SP, Kijevčanin MLj. Experimental measurements and modelling of volumetric properties, refractive index and viscosity of selected binary systems with butyl lactate at 288.15–323.15 K and atmospheric pressure. New UNIFAC-VISCO interaction parameters. Thermochim Acta. 2013; 562: 42– 55.
Živković EM, Kijevčanin MLj, Radović IR, Šerbanović SP, Djordjević BD. Viscosity of the binary systems 2-methyl-2-propanol with n-alkanes at T = (303.15, 308.15, 313.15, 318.15 and 323.15) K: prediction and correlation – New UNIFAC–VISCO interaction parameters. Fluid Phase Equilib. 2010; 299: 191–197.
Redlich O, Kister AT. Algebraic representation of thermodynamic properties and the classification of solutions. Ind Eng Chem. 1948; 40: 345–348.
Susial P, García-Vera D, Susial R, Castillo VD, Estupiñan EJ, Apolinario JC, Rodríguez-Henríquez JJ. Experimental Determination of Vapor-Liquid Equilibria. Binary Systems of Methyl Acetate, Ethyl Acetate, and Propyl Acetate with 1-Propanol at 0.6 MPa. J Chem Eng Data. 2013; 58: 2861-2867.
Nikam PS, Mahale TR, Hasan M. Density and Viscosity of Binary Mixtures of Ethyl Acetate with Methanol, Ethanol, Propan-1-ol, Propan-2-ol, Butan-1-ol, 2-Methylpropan-1-ol, and 2-Methylpropan-2-ol at (298.15, 303.15, and 308.15) K. J Chem Eng Data. 1996; 41: 1055-1058.
Mariano A, Postigo M, Artigas H, Pardo J, Royo FM. Densities and Viscosities of the Ternary Mixture (Benzene + 1-Propanol + Ethyl Acetate) at 298.15 K. Phys Chem Liq. 2000; 38: 567-581.
Murti PS, van Winkle M. Vapor-Liquid Equilibria for Binary Systems of Methanol, Ethyl Alcohol, 1-Propanol, and 2-Propanol with Ethyl Acetate and 1-Propanol-Water. Ind Eng Chem Chem Eng Data Ser. 1958; 3: 72-81.
Bahadur I, Deenadayalu N, Tywabi Z, Sen S, Hofman T. Volumetric properties of ternary (IL + 2-propanol or 1-butanol or 2-butanol + ethyl acetate) systems and binary (IL + 2-propanol or 1-butanol or 2-butanol) and (1-butanol or 2-butanol + ethyl acetate) systems. J Chem Thermodyn. 2012; 49: 24-38.
Susial P, Estupiñan EJ, Castillo VD, Rodríguez-Henríquez JJ, Apolinario JC. Experimental Determination of Densities and Isobaric Vapor-Liquid Equilibria of Methyl Acetate and Ethyl Acetate with Alcohols (C3 and C4) at 0.3 MPa. Int J Thermophys. 2013; 34: 1906-1917.
Fermeglia M, Lapasin R. Excess Volumes and Viscosities of Binary Mixtures of Organics. J Chem Eng Data. 1988; 33: 415-417.
Litkenhous EE, Van Arsdale JD, Hutchison Jr. IW. The Physical Properties of the Ternary System Butyl Alcohol-Ethyl Acetate-Toluene. J Phys Chem. 1940; 44: 377-388.
Ghael NY, Gardas RL, Oswal SL. Volumetric and transport properties of ternary mixtures containing 1-alkanol + ethyl ethanoate + cyclohexane at 303.15 K: Experimental data, correlation and prediction by ERAS model. Thermochim Acta. 2009; 491: 44-57.
Kijevčanin MLj, Djordjević BD, Radović IR, Živković EM, Tasić AZ, Šerbanović SP. Modelling of volumetric properties of organic mixtures based on molecular interactions. In: Meghea A, ed. Molecular Interactions. Rijeka, Croatia: InTech; 2012: 3-24.
Fort RJ, Moore WR. Adiabatic Compressibilities of Binary Liquid Mixtures. Trans Faraday Soc. 1965; 61: 2102-2111.