Preparation and properties of hydrogen peroxide oxidized starch for industrial use
Article Sidebar
Main Article Content
Abstract
Oxidized starch, an additive used in paper manufacturing and products for construction industry, is usually produced using harmful oxidant, such as hypochlorites or periodates. In this study, a simple and efficient eco-friendly laboratory and industrial procedures for starch oxidation were developed. The procedure involves application of small amounts of more environmentally friendly oxidant, hydrogen peroxide, a novel special metal complex catalyst such as copper(II) citrate and copper(II) ricinoleate and biobased plasticizers. Optimization procedure, with respect to the quantity of hydrogen peroxide and temperature in the presence of iron(II) sulphate catalyst, was performed by using the response surface methodology. Comparative analysis of the use of the other catalysts that is copper(II) sulphate, copper(II) citrate and copper(II) ricinoleate, indicated copper(II) citrate as the catalyst of choice. Improvement of starch is achieved using three plasticizers: ricinoleic acid (RA), diisopropyl tartarate, as well as epoxidized soybean, linseed and sunflower oils. The effects of hydrogen peroxide and catalyst concentrations, as well as the reaction temperature in the presence of naturally based plasticizers on the physicochemical, thermal and morphological properties of oxidized starch are presented. According to the results obtained in initial experiments, the optimal industrial process is based on the use of copper(II) citrate (0.1 %) as a catalyst and RA (3 %) as a plasticizer.
Article Details
Issue
Section
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
Authors grant to the Publisher the following rights to the manuscript, including any supplemental material, and any parts, extracts or elements thereof:
- the right to reproduce and distribute the Manuscript in printed form, including print-on-demand;
- the right to produce prepublications, reprints, and special editions of the Manuscript;
- the right to translate the Manuscript into other languages;
- the right to reproduce the Manuscript using photomechanical or similar means including, but not limited to photocopy, and the right to distribute these reproductions;
- the right to reproduce and distribute the Manuscript electronically or optically on any and all data carriers or storage media – especially in machine readable/digitalized form on data carriers such as hard drive, CD-Rom, DVD, Blu-ray Disc (BD), Mini-Disk, data tape – and the right to reproduce and distribute the Article via these data carriers;
- the right to store the Manuscript in databases, including online databases, and the right of transmission of the Manuscript in all technical systems and modes;
- the right to make the Manuscript available to the public or to closed user groups on individual demand, for use on monitors or other readers (including e-books), and in printable form for the user, either via the internet, other online services, or via internal or external networks.
How to Cite
References
Neelam K, Vijay S, Lalit S. Various Tecnhiques for the Modification of Starch and the Application of Its Derivatives. IRJP. 2012; 3: 25–31.
Zhang YR, Wang XL, Zhao GM, Wang YZ. Preparation and properties of oxidized starch with high degree of oxidation. Carbohydr. Polym. 2012; 87: 2554–2562.
Koohatammakun N, Saengsuwan S. One pot synthesis, Characterization, Biodegradation and Effect of the Crosslinking Agent of Semi-Interpenetrating Polymer Network Hydrogel Based on PVA/Corn Starch and Acrylic Acid. GCEAS-466. 1237–1248.
Dufresne A, Castaño J. Polysaccharide nanomaterial reinforced starch nanocomposites: A review. Starch/Stärke. 2016; 68:1–19.
Gu F, Li B, Xia H, Adhikari B, Gao Q. Preparation of starch nanospheres through hydrophobic modification followed by initial water dialysis. Carbohydr. Polym. 2015; 115: 605–612.
Tester RF, Karkalas J, Qi X. Starch - Composition, fine structure and architecture. J. Cereal Sci. 2004; 39: 151–165.
Lewicka K, Siemion P, Kurcok P. Chemical modifications of starch: Microwave effect. Int. J. Polym. Sci. 2015; 2015: 1–10.
Rübsam H, Krottenthaler M, Gastl M, Becker T. An overview of separation methods in starch analysis:The importance of size exclusion chromatography and field flow fractionation. Starch/Stärke. 2012; 64: 683–695.
Bemiller JN, Lafayette W. Starch Modification: Challenges and Prospects. Starch/Stärke. 1997; 49: 127–131.
Wurzburg OB. Nutritional Aspects and Safety of Modified Food Starches. Nutrition Review. 1986; 44: 74–79.
Tharanathan RN. Starch – Value Addition by Modification Starch. Crit. Rev. Food Sci. Nutr. 2007; 8398: 371–384.
Jobling S. Improving starch for food and industrial applications. Curr. Opin.Plant Biol. 2004; 7: 210–218.
Lawal OS, Adebowale KO, Ogunsanwo BM, Barba LL, Ilo NS. Oxidized and acid thinned starch derivatives of hybrid maize: functional characteristics, wide-angle X-ray diffractometry and thermal properties. Int. J. Biol. Macromol. 2005; 35: 71–79.
Matsuguma LS, Lacerda LG, Schnitzler E, da Silva Carvalho Filho MA, Landi Franco CM, Demiate IM. Characterization of Native and Oxidized Starches of Two Varieties of Peruvian Carrot (Arracacia xanthorrhiza, B .) From Two Production Areas of Paraná State, Brazil. Braz. Arch. Biol. Technol. 2009; 52: 701–713.
Kuakpetoon D, Y. Wang Y. Characterization of Different Starches Oxidized by Research Paper. Starch/Stärke. 2001; 53: 211–218.
Hung DP, Van Phuc M, Hiep NA, Van Thanh T, Vuong NT, Nam TT, Xuan DD. Oxidized maize starch: Characterization and Its Effect on the Biodegradable Films Part II. Infrared Spectroscopy and Solubility. VJTS. 2017; 55: 395–402.
Chen Y, Kaur L, Singh J. Chemical Modification of Starch. Elsevier Ltd; 2018.
El-sheikh MA, Ramadan MA, El-shafie A. Photo-oxidation of rice starch. Part I: Using hydrogen peroxide. Carbohydr. Polym. 2010; 80: 266–269.
Wang YJ, Wang L. Physicochemical properties of common and waxy corn starches oxidized by different levels of sodium hypochlorite. Carbohydr. Polym. 2003; 52: 207–217.
Alcázar-alay SC, Meireles MAA. Physicochemical properties, modifications and applications of starches from different botanical sources. Food Sci. Technol, Campinas. 2015; 35: 215–236.
Parovuori P, Hamunen A. Oxidation of Potato Starch by Hydrogen Peroxide. Starch/Staerke. 1995; 47: 19–23.
Tolvanen P, Mäki-Arvela P, Sorokin AB, Salmi T, Murzin DY. Kinetics of starch oxidation using hydrogen peroxide as an environmentally friendly oxidant and an iron complex as a catalyst. Chemical Engineering Journal. 2009; 154: 52–59.
Wang L, Wang W, Wang Y, Xiong G. Effects of fatty acid chain length on properties of potato starch–fatty acid complexes under partially gelatinization. Int. J. Food Prop. 2018; 21: 2121–2134.
Zhang Y, Gan T, Hu H, Huang Z, Huang A, Zhu Y, Feng Z, Yang M. A green technology for the preparation of high fatty acid starch esters: Solid-phase synthesis of starch laurate assisted by mechanical activation with stirring ball mill as reactor. Ind. Eng. Chem. Res. 2014; 53: 2114–2120.
Junistia L, Sugih AK, Manurung R, Picchioni F, Janssen L P B M, Heeres HJ. Synthesis of higher fatty acid starch esters using vinyl laurate and stearate as reactants. Starch - Stärke. 2008; 60: 667–675.
Namazi H, Fathi F, Dadkhah A. Hydrophobically modified starch using long-chain fatty acids for preparation of nanosized starch particles. Sci. Iran. 2011; 18: 439–445.
Aburto J, Hamaili H, Mouysset-Baziard G, Senocq F, Alric I, Borredon E. Free-solvent Synthesis and Properties of Higher Fatty Esters of Starch – Part 2. Starch - Stärke. 1999; 51: 302–307.
Aburto J, Alric I, Borredon E. Preparation of Long-chain Esters of Starch Using Fatty Acid Chlorides in the Absence of an Organic Solvent. Starch - Stärke. 1999; 51: 132–135.
Kaur M, Oberoi DPS, Sogi DS, Gill BS. Physicochemical, morphological and pasting properties of acid treated starches from different botanical sources. J. Food Sci. Technol. 2011; 48: 460–465.
Luo F, Huang Q, Fu X, Zhang L, Yu S. Preparation and characterisation of crosslinked waxy potato starch. Food Chem. 2009; 115: 563–568.
Emeje M, Kalita R, Isimi C, Buragohain A, Kunle O, Ofoefule S. Synthesis, Physicochemical Characterization and Functional Properties of an Esterified Starch from an Underutilized Source in Nigeria. Afr. J. Food Agric. Nutr. Dev. 2012; 12: 7001–7018.
Garrido LH, Schnitzler E. Zortéa MEB, de Souza Rocha R, Demiate IM. Physicochemical properties of cassava starch oxidized by sodium hypochlorite. J. Food Sci. Technol. 2012; 51:2640–2647.
Liu J, Wang B, Lin L, Zhang J, Liu W, Xie J, Ding Y. Functional , physicochemical properties and structure of cross-linked oxidized maize starch. Food Hydrocoll. 2014; 36: 45–52.
Kweon D, Choi J, Kim E, Lim S. Adsorption of divalent metal ions by succinylated and oxidized corn starches. Carbohydr. Polym. 2001, 46: 171–177.
Hui R, Qi-he C, Ming-liang F, Qiong X, Guo-qing H. Preparation and properties of octenyl succinic anhydride modified potato starch. Food Chem. 2009; 114: 81–86.
A. Para. Complexation of metal ions with dioxime of dialdehyde starch. Carbohydr. Polym. 2004; 57: 277–283.
Witek-Krowiak A, Chojnacka K, Podstawczyk D, Dawiec A, Pokomeda K. Application of response surface methodology and artificial neural network methods in modelling and optimization of biosorption process. Bioresour. Technol. 2014; 160: 1 –11.
Jafari SA, Cheraghi S, Mirbakhsh M, Mirza R, Maryamabadi A. Employing Response Surface Methodology for Optimization of Mercury Bioremediation by Vibrio parahaemolyticus PG02 in Coastal Sediments of Bushehr, Iran. Soil Air Water. 2015; 43: 118–126.
Kaur M, Oberoi DPS, Sogi DS, Gill BS. Physicochemical, morphological and pasting properties of acid treated starches from different botanical sources. J. Food Sci. Technol. 2011; 48: 460–465.
Ayucitra A. Preparation and Characterisation of Acetylated Corn Starches. Int. J. Chem. Eng. Appl. 2012; 3: 156–159.
Soliman AAA, El-Shinnawy NA, Mobarak F. Thermal behaviour of starch and oxidized starch. Thermochimica Acta. 1997; 296: 149–153.
Lluch AV, Felipe AM, Greus AR, Cadenato A, Ramis X, Salla MJ. Thermal Analysis Characterization of the Degradation of Biodegradable Starch Blends in Soil. J. Appl. Polym. Sci. 2005; 96: 358–371.
Soares RMD, Lima AMF, Oliveira RVB, Pires ATN, Soldi V. Thermal degradation of biodegradable edible films based on xanthan and starches from different sources. Polym. Degrad. Stabil. 2005; 90: 449–454.
N. Koga. Kinetic analysis of thermoanalytical data by extrapolating to infinite temperature. Thermochimica Acta. 1995; 258:145–159.
Liu H, Xie F, Yu L, Chen L, Li L. Thermal processing of starch-based polymers. Prog. Polym. Sci. 2009; 34: 1348–1368.
Fang J, Fowler P, Tomkinson J, Hill CAS. The preparation and characterisation of a series of chemically modified potato starches. Carbohydr. Polym. 2002; 47: 245–252.
Kovačević T, Rusmirović JD, Tomić N, Marinović-Cincović M, Kamberović Ž, Tomić M, Marinković A. New composites based on waste PET and non-metallic fraction from waste printed circuit boards: Mechanical and thermal properties. Compos. Part B Eng. 2017; 127: 1–14.
Zuo Y, Gu J, Yang L, Qiao Z, Tan H, Zhang Y. Synthesis and characterization of maleic anhydride esterified corn starch by the dry method. Int. J. Biol. Macromol. 2013; 62: 241–247.