Characterization of glycidyl methacrylate based magnetic nanocomposites
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Magnetic and non-magnetic macroporous crosslinked copolymers of glycidyl methacrylate and trimethylolpropane trimethacrylate were prepared by suspension copolymerization and functionalized with diethylenetriamine. The samples were characterized by mercury porosimetry, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy analysis (FTIR-ATR), thermogravimetric analysis (TGA), X-ray diffractometry (XRD), atomic force microscopy (AFM), transmission electron microscopy (TEM) and SQUID magnetometry. The FTIR-ATR analysis of synthesized magnetic nanocomposites confirmed the presence of magnetite and successful amino-functionalization. Non-functionalized and amino-functionalized nanocomposites exhibited superparamagnetic behavior at 300 K, with a saturation magnetization of 5.0 emu/g and 2.9 emu/g, respectively. TEM analysis of the magnetic nanocomposite has shown that magnetic nanoparticles were homogeneously dispersed in the polymer matrix. It was demonstrated that incorporation of magnetic nanoparticles enhanced the thermal stability of the magnetic nanocomposite in comparison to the initial non-magnetic macroporous copolymer.
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Li S, Qin J, Fornara A, Toprak , Muhammed M, Kim DK. Synthesis and magnetic properties of bulk transparent PMMA/Fe-oxide nanocomposites. Nanotechnology. 2009; 20: 185607. doi: 10.1088/0957-4484/20/18/185607.
Mincheva R, Stoilova O, Penchev H, Ruskov T, Spirov I, Manolova N, Rashkov I. Synthesis of polymer-stabilized magnetic nanoparticles and fabrication of nanocomposite fibers thereof using electrospinning. Eur Polym J. 2008; 44: 615-627.
Marangoni V., Martins MVA, Souza JA, Oliveira ON, Zucolotto V, Crespilho FN. The processing of polyelectrolyte-covered magnetite nanoparticles in the form of nanostructured thin films. J Nanoparticle Res. 2012; 14: 1-10.
Wilson JL, Poddar P, Frey NA, Srikanth H, Mohomed K, Harmon JP, Kotha S, Wachsmuth J. Synthesis and magnetic properties of polymer nanocomposites with embedded Iron nanoparticles. J Appl Phys. 2004; 95: 1439-1443.
Zhou L, Yuan J, Yuan W, Sui X, Wu S, Li Z, Shen D. Synthesis, characterization, and controllable drug release of pH-sensitive hybrid magnetic nanoparticles. J Magn Magn Mater. 2009; 321: 2799-2804.
Elwakeel KZ, Guibal E. Potential use of magnetic glycidyl methacrylate resin as a mercury sorbent: From basic study to the application to wastewater treatment. J Environ Chem Eng. 2016; 4: 3632-3645.
Philippova O, Barabanova A, Molchanov V, Khokhlov A. Magnetic polymer beads: Recent trends and developments in synthetic design and applications. Eur Polym J. 2011; 47: 542-559.
Nguyen VH, Haldorai Y, Pham QL, Shim JJ. Supercritical fluid mediated synthesis of poly(2-hydroxyethyl methacrylate)/Fe3O4 hybrid nanocomposite. Mater Sci Eng B Solid-State Mater Adv Technol. 2011; 176: 773-778.
Lee MA, Park BJ, Chin IJ, Choi HJ. Polymer modified hematite nanoparticles for electrophoretic display. J Electroceramics. 2009; 23: 474-477.
Deng J, Ding X, Zhang W, Peng Y, Wang J, Long X, Li P, Chan ASC. Magnetic and conducting Fe3O4–cross-linked polyaniline nanoparticles with core–shell structure. Polymer. 2002; 43: 2179-2184.
Vukoje ID, Džunuzović ES, Lončarević DR, Dimitrijević S, Ahrenkiel SP, Nedeljković JM. Synthesis, characterization, and anti-microbial activity of silver nanoparticles on poly(GMA‐co‐EGDMA) polymer support. Polym. Composite. 2015; 38: 1206-1214.
Webb PA, Orr C. Analytical Methods in Fine Particle Technology. Norcross, Georgia, United States: Micromeritics Instrument Corp; 1997.
Marković BM, Vuković ZM, Spasojević V V, Kusigerski VB, Pavlović VB, Onjia AE, Nastasović AB. Selective magnetic GMA based potential sorbents for molybdenum and rhenium sorption. J Alloys Compd. 2017; 705; 38-50.
Marković BM, Stefanović IS, Hercigonja RV, Pergal MV, Marković JP, Onjia AE, Nastasović AB. Novel hexamethylene diamine-functionalized macroporous copolymer for chromium removal from aqueous solutions. Polym Int. 2017; 66: 679-689.
Nastasović A, Sandić Z, Suručić Lj, Maksin D, Jakovljević D, Onjia A. Kinetics of hexavalent chromium sorption on amino-functionalized macroporous glycidyl methacrylate copolymer. J Hazard Mater. 2009; 171; 153-159.
Kim D, Lee DY, Lee K, Choe S. Effect of Crosslinking Agents on the Morphology of Polymer Particles Produced by One-Step Seeded Polymerization. Macromol Res. 2009; 17: 250-258.
Mustata F, Tudorachi N, Bicu I. Thermosetting resins obtained via sequential photo and thermal crosslinking of epoxy resins. Curing kinetics, thermal properties and morphology. Compos Part B Eng. 2013; 55: 470-478.
Rao SS, Jeyapal SG, Rajiv S. Biodegradable electrospun nanocomposite fibers based on Poly(2-hydroxy ethyl methacrylate) and bamboo cellulose. Compos Part B Eng. 2014; 60: 43-48.
Meiorin C, Muraca D, Pirota KR, Aranguren MI, Mosiewicki MA. Nanocomposites with superparamagnetic behavior based on a vegetable oil and magnetite nanoparticles. Eur Polym J. 2014; 53: 90-99.
Metin AU. Synthesis, physical properties, and application of aminated poly(glycidyl methacrylate)/zeolite composite. Polym. Composite. 2016; 37: 2313-2322.
Chen Y, Qian J, Zhang K, Liu X, Zhuang Q, Han Z. In situ synthesis and characterization of fluorinated polybenzobisoxazole/silica‐coated magnetic Fe3O4 nanocomposites exhibiting enhanced electromagnetic wave absorption property. Polym Composite. 2015; 36: 884-891.
Pourjavadi A, Abedin-Moghanaki A. Ultrafast and efficient removal of cationic dyes using a magnetic nanocomposite based on functionalized cross-linked poly(methylacrylate). React Funct Polym. 2016; 105: 95-102.
Raposo M, Ferreira Q, Ribeiro PA. A guide for atomic force microscopy analysis of soft-condensed matter. In: A. Méndez-Vilas and J. Díaz, Eds. Modern Research and Educational Topics in Microscopy. Badajoz, Spain: Formatex; 2007: 758–769.
Shukla P, Bajpai AK, Bajpai R. Structural, morphological, thermal and mechanical characterization of cellulose acetate–poly (acrylonitrile) semi interpenetrating polymer network (IPN) membranes and study of their swelling behavior. Polym Bull. 2016; 73: 2245-2264.
Vatanpour V, Esmaeili M, Davood Abadi Farahani MH, Fouling reduction and retention increment of polyethersulfone nanofiltration membranes embedded by amine-functionalized multi-walled carbon nanotubes. J Membrane Sci. 2014; 466: 70-81.
Donescu D, Raditoiu V, Spataru CI, Somoghi R, Ghiurea M, Radovici C, Fierascu RC, Schinteie G, Leca A, Kuncser V. Superpara-magnetic magnetite-divinylbenzene-maleic anhydride copolymer nanocomposites obtained by dispersion polymerization. Eur Polym J. 2012; 48: 1709-1716.
Darwish MSA, Bakry A, Kolek O, Martinová L, Stibor I. Electrospun functionalized magnetic polyamide 6 composite nanofiber: Fabrication and stabilization. Polym Composite. 2017; doi: 10.1002/pc.24647.
Mahdieh A, Mahdavian AR, Salehi-Mobarakeh H. Chemical modification of magnetite nanoparticles and preparation of acrylic-base magnetic nanocomposite particles via miniemulsion polymerization. J Magn Magn Mater. 2017; 426: 230-238.
Si S, Li C, Wang X, Yu D, Peng Q, Li Y. Magnetic monodisperse Fe3O4 nanoparticles. Cryst Growth Des. 2005; 5: 391-393.
Bezdorozhev O, Kolodiazhnyi T, Vasylkiv O. Precipitation synthesis and magnetic properties of self-assembled magnetite-chitosan nanostructures. J Magn Magn Mater. 2017; 428: 406-411.
Paredes B, González S, Rendueles M, Villa-García MA, Díaz M. Influence of the amination conditions on the textural properties and chromatographic behaviour of amino-functionalized glycidyl methacrylate-based particulate supports. Acta Mater. 2003; 51: 6189-6198.
Terrin MM, Poli AL, Horn Jr MA, Neumann MG, Cavalheiro ETG, Correa IC, Schmitt CC. Effect of the loading of organomodified clays on the thermal and mechanical properties of a model dental resin. Mater Res. 2016; 19: 40-44.
Maciejewska M. Thermal properties of TRIM–GMA copolymers with pendant amine groups. J Therm Anal Calorim. 2016; 126; 1777-1785.
Podkościelna B. New crosslinked hydrogels derivatives of 2-hydroxyethyl methacrylate: Synthesis, modifications and properties. Express Polym Lett. 2012; 6: 759-771.
Safajou-Jahabkhanemlou M, Abbasi F, Salami-Kalajahi M. Synthesis and characterization of poly(methyl methacrylate)/graphene‐based thermally expandable microcapsules. Polym Composite. 2018; 39: 950-960.
Patra N, Salerno M, Cozzoli PD, Barone AC, Ceseracciu L, Pignatelli F, Carzino R, Marini L, Athanassiou A. Thermal and mechanical characterization of poly(methyl methacrylate) nanocomposites filled with TiO2 nanorods. Compos Part B Eng. 2012; 43: 3114-3119.
Marković BM, Janković DLj, Vukadinović AA, Ranđelović DV, Maksin DD, Spasojević VV, Nastasović AB. A novel macroporous polymer–inorganic nanocomposite as a sorbent for pertechnetate ions. RSC Adv. 2017; 7: 21412- 21421.