Fenton proces za tretman industrijskih otpadnih voda u disperznim sistemima (Pregledni rad)

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Ana Popović
Sonja Milićević
Vladan Milošević
Branislav Ivošević
Jelena Čarapić
Vladimir Jovanović
Dragan Povrenović

Abstract

Otpadna voda industrijskih procesa u sebi sadrži teško razgradiva organska jedinjenja. Ovakva jedinjenja su izgrađena od molekula sa dugim nizom ugljenikovih atoma, uz prisustvo različitih funkcionalih grupa. Uklanjanje ovih jedinjenja iz otpadne vode, tretmanima kao što su hemijski i biološki, u poslednje vreme zamenjuje se nekonvencionalnim metodama, čija je efikasnost daleko veća. Napredni oksidacioni procesi nemaju ograničenja u poređenju sa konvencionalnim metodama, u pogledu nastajanja neželjenih nus-proizvoda pri minerali­zaciji toksičnih zagađujućih supstanci. Fenton proces, ili primena Fentonovog reagensa, izdvojio se od ostalih naprednih oksidacionih procesa kao najprimenjivaniji, zbog svoje jed­nostavnosti, ekonomičnosti i dostupnosti gvožđa i vodonik-peroksida koji se pri ovom procesu koriste. Fentonov reagens je katalitičko-oksidativna smeša jona gvožđa i vodonik-peroksida. Joni gvožđa Fe2+ iniciraju i katalizuju dekompoziciju H2O2 do hidroksil radikala koji ima sposobnost da oksiduje organsku materiju do ugljek-dioksida i vode. Tokom Fenton procesa, osim hidroksil radikala generišu se i druge radikalne vrste koje takođe učestvuju u razgradnji organske materije. Efikasnost Fenton procesa zavisi od fizičkih i hemijskih karak­teristika zagađujuće materije koja podleže tretmanu, kao i operativnih uslova u kojima se proces izvodi. Formiranje mulja, koji čine hidroksidi gvožđa, predstavlja glavni nedostatak ovog procesa. Alternativno rešenje ovog problema, jeste primena Fenton procesa u disperznim sistemima.

Cilj ovog rada je pregled moguće primene Fenton procesa u disperznim sistemima sa akcentom na upotrebi različitih vrsta katalizatora. Kontrolisanjem parametara Fenton procesa u disperznim sistemima, kao što su vrednost pH, temperatura, koncentracija vodonik-peroksida i reakciono vreme, povećava se efikasnost razgradnje složenih organskih materija u otpadnoj vodi. Povećanje efikasnosti ovakvog sistema ima značajnu ulogu za njegovu primenu u komercijalne svrhe.

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How to Cite
Popović, A., Milićević, S., Milošević, V., Ivošević, B., Čarapić, J., Jovanović, V., & Povrenović, D. (2019). Fenton proces za tretman industrijskih otpadnih voda u disperznim sistemima (Pregledni rad). HEMIJSKA INDUSTRIJA (Chemical Industry), 73(1), 47–62. https://doi.org/10.2298/HEMIND181019005P
Section
Environmental Engineering - Waste Water Treatment
Author Biography

Ana Popović, Institut za tehnologiju nuklearnih i drugih mineralnih sirovina (ITNMS), Beograd

Završila Fakultet tehničkih nauka, smer inženjerstvo zaštite životne sredine, Univerzitet u Novom Sadu, Master na Tehnološko-metalurškom fakultetu U Beogradu, na smeru inženjerstvo zaštite životne sredine. Trenutno na doktorskim studijama na Tehnološko-metalurškom fakultetu U Beogradu, na smeru inženjerstvo zaštite životne sredine.

Zaposlena u Institutu za tehnologiju nuklearnih i drugih mineralnih sirovina (ITNMS), Beograd, gde se bavi tehnologijama prečišćavanja otpadnih voda.

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