Determination of residues of sulfonylurea herbicides in soil by using microwave-assisted extraction and high performance liquid chromatographic method

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Published: Sep 25, 2017
DOI: https://doi.org/10.2298/HEMIND160224039G
Keywords:
sulfonylurea herbicide, microwave-assisted extraction, HPLC-UV-DAD, soil, dissipation

Main Article Content

Nada L. Grahovac
Institute of Field and Vegetable Crops, Novi Sad
Zorica S. Stojanović
University of Novi Sad, Faculty of Technology, Novi Sad
Snežana Ž. Kravić
University of Novi Sad, Faculty of Technology, Novi Sad
Dejan Z. Orčić
University of Novi Sad, Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Novi Sad
Zvonimir J Suturović
University of Novi Sad, Faculty of Technology, Novi Sad
Ankica Đ. Kondić-Špika
Institute of Field and Vegetable Crops, Novi Sad
Jovica R. Vasin
Institute of Field and Vegetable Crops, Novi Sad
Dragana B. Šunjka
University of Novi Sad, Faculty of Agriculture, Novi Sad
Snežana P. Jakšić
Institute of Field and Vegetable Crops, Novi Sad
Miloš M. Rajković
Institute of Field and Vegetable Crops, Novi Sad
Nenad M. Grahovac
University of Novi Sad, Faculty of Technical Sciences, Department of Technical Mechanics, Novi Sad

Abstract

A modified method for the analysis of nicosulfuron, rimsulfuron and prosulfuron was developed and validated by using microwave-assisted extraction (MAE) and ultra-perform­ance liquid chromatography with diode array detection in the ultraviolet region (HPLC-UV-DAD). The most important experimental parameters of extraction procedure and HPLC-UV-DAD technique were optimised in respect to those sulfonylurea herbicides. High rec­overies of the microwave-assisted extraction were obtained by using a dichloromethaneacetonitrile mixture (2:1 volume ratio) acidified with acetic acid (0.8 vol.%) with the addit­ion of urea. The mean recoveries at three spiking levels ranged from 97.47 to 98.76% for nicosulfuron, 97.88 to 99.17% for rimsulfuron and from 97.91 to 99.83% for prosulfuron. The limits of detection of nicosulfuron, rimsulfuron and prosulfuron were 0.95, 0.91 and 0.89 µg kg–1, respectively. The accuracy of the developed method was confirmed by HPLC coupled with tandem mass spectrometry parallel analyses. The developed method was used to investigate the dissipation dynamics of sulfonylurea herbicides in the real field trials in Vojvodina Province, Serbia. The obtained half-lives were 0.05, 0.23 and 0.15 days for recommended dose application of nicosulfuron, rimsulfuron and prosulfuron, respect­ively. Low residues and short half-life in soil suggested that the risk to sensitive rotational crops after application of those sulfonylurea herbicides is low when they are used in the appropriate dosages.

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How to Cite
Grahovac, N. L., Stojanović, Z. S., Kravić, S. Ž., Orčić, D. Z., Suturović, Z. J., Kondić-Špika, A. Đ., Vasin, J. R., Šunjka, D. B., Jakšić, S. P., Rajković, M. M., & Grahovac, N. M. (2017). Determination of residues of sulfonylurea herbicides in soil by using microwave-assisted extraction and high performance liquid chromatographic method. HEMIJSKA INDUSTRIJA (Chemical Industry), 71(4), 289–298. https://doi.org/10.2298/HEMIND160224039G
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Vol. 71 No. 4 (2017)
Section
General
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