Iron-based metal organic framework as an effective lead ions remover from aqueous solution: Thermodynamic and kinetic studies
Article Sidebar
Main Article Content
Abstract
Metal organic frameworks (MOFs) based on iron as a central metal ion and 1,2,4,5-tetrabenzenecarboxylic acid as ligand was successful synthesized, characterized and studied as adsorbent for the removal of lead ions in aqueous solution. Characterization of Fe-MOF was attained by SEM, EDX, TGA and FT-IR techniques. EDX spectrum showed the presence of C, O and Fe, which may facilitate in creating charges and functionalities on the surface of the Fe-MOF for adsorption. The kinetic and thermodynamic parameters were also investigated. The results showed that Fe-MOF has a high Pb2+ adsorption affinity. The removal of Pb2+ from aqueous solutions varied with concentration, contact time and temperature. All adsorption studies were carried out in batch experiments.
Article Details
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
Authors grant to the Publisher the following rights to the manuscript, including any supplemental material, and any parts, extracts or elements thereof:
- the right to reproduce and distribute the Manuscript in printed form, including print-on-demand;
- the right to produce prepublications, reprints, and special editions of the Manuscript;
- the right to translate the Manuscript into other languages;
- the right to reproduce the Manuscript using photomechanical or similar means including, but not limited to photocopy, and the right to distribute these reproductions;
- the right to reproduce and distribute the Manuscript electronically or optically on any and all data carriers or storage media – especially in machine readable/digitalized form on data carriers such as hard drive, CD-Rom, DVD, Blu-ray Disc (BD), Mini-Disk, data tape – and the right to reproduce and distribute the Article via these data carriers;
- the right to store the Manuscript in databases, including online databases, and the right of transmission of the Manuscript in all technical systems and modes;
- the right to make the Manuscript available to the public or to closed user groups on individual demand, for use on monitors or other readers (including e-books), and in printable form for the user, either via the internet, other online services, or via internal or external networks.
How to Cite
References
T.K. Naiya, A.K. Bhattacharya, S. Mandal, S.K. Das, The sorption of lead (II) ions on rice husk ash, J. Hazard. Mater. 163 (2009) 1254–1264.
R. Ayyappan, A.C. Sophia, K. Swaminathan, S. Sandhya, Removal of Pb(II) from aqueous solution using carbon derived from agricultural wastes, Process Biochem. 40 (2005) 1293–1299.
J. Goel, K. Kadirvelu, C. Rajagopal, V.K. Garg, Removal of lead (II) by adsorption using treated granular activated carbon: batch and column studies, J. Hazard. Mater. 125 (2005) 211–220.
B.L. Martins, C.C.V. Cruz, A.S. Luna, C.A. Henriques, Sorption and desorption of Pb 2+ ions by dead Sargassum sp. biomass, Biochem. Eng. J. 27 (2006) 310–314.
S. Tunali, T. Akar, A.S. Ozcan, I. Kiran, A. Ozcan, Equi-librium and kinetics of biosorption of lead(II) from aqueous solutions by Cephalosporium aphidicola, Sep. Purif. Technol. 47 (2006) 105–112.
L. Largitte, J. Laminie, Modelling the lead concentration decay in the adsorption of lead onto a granular activated carbon, J. Environ. Chem. Eng. 3 (2015) 474–481.
R. Kumar, P. Pal, Response surface-optimized Fentons pre-treatment for chemical precipitation of struvite and recycling of water through downstream nanofiltration, Chem. Eng. J. 210 (2012) 33–44.
Y.C. Lai, Y.R. Chang, M.L. Chen, Y.K. Lo, J.Y. Lai, D.J. Lee, Poly(vinyl alcohol) and alginate cross–linked matrix with immobilized Prussian blue and ion exchange resin for cesium removal from waters, Bioresour. Technol. 214 (2016) 192–198.
J. Zhang, H. Yu, X. Quan, S. Chen, Y. Zhang, Ceramic membrane separation coupled with catalytic ozonation for tertiary treatment of dyestuff wastewater in a pilot-scale study, Chem. Eng. J. 301 (2016) 19–26.
G. Pandey, S. Mukhopadhyay, A.U. Renjith, J.M. Joshi, K.T. Shenoy, Recovery of Hf and Zr from slurry waste of zirconium purification plant using solvent extraction, Hydrometallurgy 163 (2016) 61–68.
J.N. Hakizimana, B. Gourich, C. Vial, P. Drogui, A. Oumani, J. Naja, L. Hilali, Assessment of hardness, microorganism and organic matter removal from seawater by electrocoagulation as a pretreatment of desalination by reverse osmosis, Desalination 393 (2016) 90–101.
E. Diaz, M. Cebriana, A. Bahamonde, M. Faraldos, A. F. Mohedano, J. A. Casas, J. J. Rodriguez, Degradation of organochlorinated pollutants in water by catalytic hydrodechlorination and photocatalysis, Catal. Today 266 (2016) 168–174.
S. Walker, R. M. Narbaitz, Hollow fiber ultrafiltration of Ottawa River water: Floatation versus sedimentation pretreatment, Chem. Eng. J. 288 (2016) 228–237.
N. Tewari, P. Vasudevan, B.K. Guha, Study on biosorption of Cr(VI) by Mucor hiemalis, Biochem. Eng. J. 23 (2005) 185–192.
C.F. Brasquet, K. Kadirvelu, P.L. Cloirec, Removal of metal ions from aqueous solution by adsorption onto activated carbon cloths: adsorption competition with organic matter, Carbon 40 (2002) 2387–2392.
N.R. Bishnoi, M. Bajaj, N. Sharma, A. Gupta, Adsorption of Cr(VI) on activated rice husk carbon and activated alumina, J. Bioresour. Technol. 91 (2004) 305–307.
X.H. Do, B.K. Lee, Removal of Pb2+ using a biochar-alginate capsule in aqueous solution and capsule regeneration, J. Environ. Manage. 131 (2013) 375–382.
A. Kundu, G. Redzwan, J.N. Sahu, S. Mukherjee, B.S. Gupta, M.A. Hashim, Hexavalent chromium adsorption by a novel activated carbon prepared by microwave activation, Bioresour. 9 (2014) 1498–1518.
L.F. Marques, C.C. Correa, S.J.L. Ribeiro, M.V.D. Santos, J.D.L. Dutra, R.O. Freire, F.C. Machado, Synthesis, structural characterization, luminescent properties and theoretical study of three novel lanthanide metal–organic frameworks of Ho(III), Gd(III) and Eu(III) with 2,5-thiophenedicarboxylate anion, J. Solid State Chem. 227 (2015) 68–78.
A. Dhakshinamoorthy, M. Alvaro, H. Garcia, Aerobic oxidation of styrenes catalyzed by an iron metal organic framework, A.C.S. Catal. 1 (2011) 836–840.
R.C. Huxford, J.D. Rocca, W. Lin, Metal-organic frame-works as potential drug carriers, Curr. Opin. Chem. Biol. 14 (2010) 262–268.
C. Petit, B. Levasseur, B. Mendoza, T. Bandosz, Reactive adsorption of acidic gases on MOF/graphite oxide composites, J. Microporous Mesoporous Mater. 154 (2012) 107–112.
Y. Yu, X.M. Zhang, J.P. Ma, Q.K. Liu, P. Wang, Y.B. Dong, Cu(I)-MOF: naked-eye colorimetric sensor for humidity and formaldehyde in single-crystal-to-single-crystal fashion, Chem. Commun. 50 (2014) 1444–1446.
N. Bakhtiari, S. Azizian, S.M. Alshehri, N.L. Torad, V. Malgras, Y. Yamauchi, Study on adsorption of copper ion from aqueous solution by MOF-derived nanoporous carbon, Microporous Mesoporous Mater. 217 (2015) 173–177.
A. Maleki, B. Hayati, M. Naghizadeh, S.W. Joo, Adsorption of hexavalent chromium by metal organic frame-works from aqueous solution, J. Ind. Eng. Chem. 28 (2015) 211–216.
K.H. Chu, M.A. Hashim, Desorption of Copper from Polyvinyl Alcohol‐Immobilized Seaweed Biomass, Acta Biotechnol. 21 (2001) 295–306.
V.J.P. Poots, G. Mckay, J.J. Healy, Removal of Basic Dye from Effluent Using Wood as an Adsorbent, J. Water. Res. 10 (1978) 1067–1070.
D. Wankasi, M. Horsfall, A.I. Spiff, Sorption kinetics of Pb2+ and Cu2+ ions from aqueous solution by Nipah palm (Nypa fruticansWurmb) shoot biomass, Chem. Tech. J. 9 (2006) 587–592.
D. Wankasi, Adsorption, A Guide to Experimental Data Analysis, Ano Publication Company, Nigeria, 2013, pp. 40–43.
M. Mazaj, G. Mali, M. Rangus, E. Zunkovic, V. Kaucic, N.Z. Logar, Spectroscopic studies of structural dynamics induced by heating and hydration: a case of calcium terephthalate metal-organic framework, J. Phys. Chem. 117 (2013) 7552–7564.
P.N. Palanisamy, A. Agalya, P. Sivakumar, Polymer composite a potential biomaterial for the removal of reactive dye, E. J. Chem. 9 (2012) 1823–1834.
Y. Pei, X. Chen, D. Xiong, S. Liao, G. Wang, Removal and recovery of toxic silver ion using deep-sea bacterial generated biogenic manganese oxides, PLoS One 8 (2013), e81627; doi: 10.1371/journal.pone.0081627.