Reciklaža katodnog materijala LiCo0,59Mn0,26Ni0,15O2 iz istrošenih litijum-jonskih baterija metodom sagorevanja citratnog gela

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Jelena V. Senćanski
Milica J. Vujković
Ivana B. Stojković
Divna M. Majstorović
Danica V. Bajuk-Bogdanović
Ferenc T. Pastor
Slavko V. Mentus

Abstract

Nekoliko istrošenih komercijalnih Li-jonskih baterija reciklirano je relativno brzim, ekono­mičnim i jednostavnim postupkom. Posle mehaničkog rastavljanja komponenti komercijal­nih baterija sa Li(Co–Mn–Ni)O2 kao katodnim materijalom, ispitana su tri načina odvajanja katodnog materijala od Al kolektora: 1. rastvaranjem Al podloge u alkalnoj sredini, 2. ispi­ranje pomoću rastvarača N-metilpirolidona i 3. termičkim razaranjem veziva na 700 °C. U pogledu prinosa datog materijala postupak rastvaranja u alkalnoj sredini se pokazao kao najefikasniji. Hemijski sastav pojedinačnih komponenti baterija (košuljice, Al/Cu kolektora, katodnog materijala,...) određen je atomskom apsorpcionom spektrometrijom, pri čemu su ispitivane komponente prethodno prevedene u stanje rastvora. Nakon odvajanja katodnog materijala i prevođenja u stanje nitratnog rastvora ponovo je izvršena sinteza metodom sagorevanja citratnog gela. Dobijeni proizvod je, nakon žarenja na 750 °C, karakterisan metodama difrakcije X-zraka i ramanske spektroskopije. Dobijen je proizvod stehiomet­rijskog sastava LiCo0,59Mn0,26Ni0,15O2, heksagonalne slojevite strukture tipa α-NaFeO2. Funkcionalnost resintetisanog materijala ispitana je u 1 M rastvoru LiClO4 u propilen-kar­bonatu, galvanostatskim punjenjem i pražnjenjem, pri gustini struje od 0,7 C. Reciklirani materijal pokazuje relativno dobre kapacitete punjenja i pražnjenja koji iznose 94,9 i 64,8 mA h g–1, redom.

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How to Cite
Senćanski, J. V., Vujković, M. J., Stojković, I. B., Majstorović, D. M., Bajuk-Bogdanović, D. V., Pastor, F. T., & Mentus, S. V. (2017). Reciklaža katodnog materijala LiCo0,59Mn0,26Ni0,15O2 iz istrošenih litijum-jonskih baterija metodom sagorevanja citratnog gela. HEMIJSKA INDUSTRIJA (Chemical Industry), 71(3), 211–220. https://doi.org/10.2298/HEMIND160418031S
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