Design and optimization of a packed bed scrubber for purification of waste gas containing ammonium Technical paper

Main Article Content

Zorana Lj. Arsenijević
https://orcid.org/0000-0003-4737-2402
Ivona R: Radović
https://orcid.org/0000-0002-2726-1564
Mirjana Lj. Kijevčanin
https://orcid.org/0000-0001-7126-3965
Tatjana S. Kaluđerović Radoićić
https://orcid.org/0000-0003-4294-0343

Abstract

In this work, a two-stage packed bed scrubber was designed and optimized for purification of industrial waste gas containing ammonia at a concentration of 1400 mg m-3. Basic material balance equations, equilibrium data, and the generalized pressure drop correlation were used for the calculation. For the analysis of different configurations, Katmar software was utilized, which uses the generalized pressure drop correlation in order to calculate the scrubber diameter based on the allowable pressure drop and proximity to flooding conditions. It was found that optimal results are achieved in a two-stage device, using 70 vol.% sulfuric acid for chemisorption of ammonia. Pall rings, 50 mm in size and made of polypropylene, were selected as a column packing. Performances of scrubbers of three column diameters (i.e., Dc=2; 2.1 and 2.2 m) were analyzed. From the aspect of the liquid phase flow, the column diameter of 2 m provides satisfactory results. According to the packing specifications, the pressure drop through the packing layer would be about 900 Pa. It was found that the pressure gradient, and therefore the total pressure drop in the column decreases with increasing the column diameter. However, as the diameter of the column increases, the minimum flow rate of the liquid phase required to wet the packed bed increases, so the required liquid flow rate increases. Taking into account all of the analyzed process parameters, as well as the required purification degree of the waste gas, the optimal configuration of the device was proposed.

Downloads

Download data is not yet available.

Article Details

How to Cite
Arsenijević, Z. L., Radović, I. R., Kijevčanin, M. L., & Kaluđerović Radoićić, T. S. (2024). Design and optimization of a packed bed scrubber for purification of waste gas containing ammonium : Technical paper. HEMIJSKA INDUSTRIJA (Chemical Industry), 78(3), 303–314. https://doi.org/10.2298/HEMIND230911019A
Section
Multiphase Systems in Chemical Engineering

References

Bhatia MV. Packed Tower and Absorption Design. In Cheremisinoff PN, Young RA, eds. Air Pollution Control and Design Handbook. New York, NY: Marcel Dekker; 1977. https://doi.org/10.1007/978-981-13-7488-3

Richards JR. Control of Gaseous Emissions. APTI Course 415. U.S. Environmental Protection Agency; 1995. https://www.4cleanair.org/wp-content/uploads/APTI/415combined.pdf

Srivastava RK, Jozewicz W, Singer C. SO2 scrubbing technologies. Environ Prog. 2001; 20(4): 219-28. https://doi.org/10.1002/ep.670200410

Wet Scrubber System Study. NTIS Report PB-213016; U.S. EPA, Research Triangle Park, NC, 1972. https://nepis.epa.gov/Exe/ZyNET.exe/9101LF9J.txt?ZyActionD=ZyDocument&Client=EPA&Index=Prior%20to%201976&Docs=&Query=&Time=&EndTime=&SearchMethod=1&TocRestrict=n&Toc=&TocEntry=&QField=&QFieldYear=&QFieldMonth=&QFieldDay=&UseQField=&IntQFieldOp=0&ExtQFieldOp=0&XmlQuery=&File=D%3A%5CZYFILES%5CINDEX%20DATA%5C70THRU75%5CTXT%5C00000023%5C9101LF9J.txt&User=ANONYMOUS&Password=anonymous&SortMethod=h%7C-&MaximumDocuments=1&FuzzyDegree=0&ImageQuality=r75g8/r75g8/x150y150g16/i425&Display=hpfr&DefSeekPage=x&SearchBack=ZyActionL&Back=ZyActionS&BackDesc=Results%20page&MaximumPages=1&ZyEntry=1&slide#

Joseph GTPE, Beachler DS. Scrubber System Operation Review., 2nd ed., North Carolina State University; 1998. https://www.studocu.com/es-mx/document/universidad-veracruzana/operaciones-fisicas-unitarias/design-review-of-absorbers-used-for-gaseous-pollutants-removal/10718576

Hesketh HD. Wet scrubbers. 2nd ed., New York, NY: Routledge; 2017. https://doi.org/10.1201/9780203733899

U.S. Environmental Protection Agency, 1998. Wet-Film (Packed Tower) Scrubbers. 2012; 1-15. www.yosemite.epa.gov/oaqps/eogtrain.nsf.gov

Schifftner KC, Hesketh HE. Wet scrubbers. United States: 1983. https://www.osti.gov/biblio/6626241

McCabe Wl, Smith JC, Harriot P Unit Operations of Chemical Engineering, McGraw-Hill International Editions, New York, 1993. ISBN 0-07-044844-2. https://evsujpiche.files.wordpress.com/2014/06/unit-operations-of-chemical-engineering-5th-ed-mccabe-and-smith.pdf

Strigle RE Jr. Packed Tower Design and Applications - Random and Structured Packings. 2nd ed., Houston, London, Paris, Zurich, Tokyo: Gulf Publishing Company; 1994. ISBN 0-88415-179-4. https://www.scribd.com/doc/81675448/Packed-Tower-Design-and-Applications-R-F-Strigle-1994

Phillips J. Control and pollution prevention options for ammonia emissions: VIGYAN Inc. (Technical Report), United States; 1995. https://www.osti.gov/biblio/104094

Hadlocon LJ, Manuzon RB, Zhao L. Optimization of ammonia absorption using acid spray wet scrubbers. Transactions of the ASABE. 2014; 57(2): 647-659. https://doi.org/10.13031/trans.57.10481

Ashtari AK, Majd AM, Riskowski GL, Mukhtar S, Zhao L. Removing ammonia from air with a constant pH, slightly acidic water spray wet scrubber using recycled scrubbing solution. Front Environ Sci Eng. 2016; 10; 3. https://doi.org/10.1007/s11783-016-0869-3

Piche S, Larachi F, Grandjean BPA. Flooding Capacity in Packed Towers: Database, Correlations, and Analysis. Ind. Eng Chem Res. 2001; 40: 476-487. https://doi.org/10.1021/ie000486s

Packed Column Calculator, Version 2.1, March 2010, Katmar Software, http://www.KatmarSoftware.com

Leva M. Tower Packings and Packed Tower Design. United States Stoneware Company: Akron, OH, 1953. https://babel.hathitrust.org/cgi/pt?id=mdp.39015000476294&seq=11

Eckert JS. How tower packings behave. Chem Eng. 1975; 2(8): 70-76. https://www.coursehero.com/file/p5fbd1p/Eckert-J-S-1975-How-tower-packings-behave-Chemical-Engineering-v-82-pp-70-Ellis/

Robbins L. Improve pressure drop prediction with a new correlation. Chem Eng Prog. 1991; 87(5): 87-90. ISSN 0360-7275. https://api.semanticscholar.org/CorpusID:113682503

The Pall Ring Company Ltd., UK. https://www.pallrings.co.uk/products/pall-rings-plastic/

Most read articles by the same author(s)