Prirodni duboki eutektički rastvarači za uklanjanje zamućenosti iz sintetičke farmaceutske otpadne vode Naučni rad
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Kontaminacija vodnih resursa otpadom aktivnih farmaceutskih sastojaka je među glavnim problemima životne sredine. Da bi se sprečili veliki poremećaji u prirodnim vodama, treba uspostaviti efikasan i ekološki prihvatljiv postupak uklanjanja zamućenja od strane uobičajenih zagađujućih materija, kao što je paracetamol. U ovoj studiji je istraživana upotreba nekoliko prirodnih dubokih eutektičkih rastvarača u cilju smanjivanja zamućenosti simulirane vode kontaminirane paracetamolom ispod standardne granice zamućenosti koju preporučuju Nacionalni standardi kvaliteta vode u Maleziji (50 NTU). Određeni su optimalni radni parametri (količina eutektičkih rastvarača, vreme mešanja i radna pH vrednost). Pod optimizovanim uslovima, korišćenje eutektičkog rastvarača na bazi stearinske kiseline dovelo je do najvećeg smanjenja zamućenosti od 97,5 %. Visoke performanse koagulacije su ispitivane na osnovu molekularne interakcije, korišćenjem COSMO-RS (CONductor like Screening MOdel for Real Solvents)
s-profila i s-potencijala (histogram raspodele gustine naelektrisanja preko molekularne površine) i pokazali su visok afinitet između eutektičkih rastvarača i paracetamola. Zaključeno je da su eutektički rastvarači obećavajući kandidati za uklanjanje zamućenosti vode izazavane prisustvom paracetamola i prikladni su u daljim istraživanjima tretmana otpadnih voda.
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Funding data
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Universiti Malaya
Grant numbers GPF015a-2023 -
Ministry of Higher Education, Malaysia
Grant numbers FRGS/1/2023/TK05/UKM/02/5
Reference
Crini G, Lichtfouse E. Advantages and disadvantages of techniques used for wastewater treatment. Environ Chem Lett. 2019; 17(1): 145-155. https://doi.org/10.1007/s10311-018-0785-9
Yao T, Gan Y, Li Q, Tan M, Shi X. Removal and recovery of triphenylmethane dyes from wastewater with temperature-sensitive magnetic ionic liquid aqueous two-phase system. J Clean Prod. 2021; 328: 129648. https://doi.org/10.1016/j.jclepro.2021.129648
Imdad S, Dohare RK. A Critical Review on Heavy Metals Removal Using Ionic Liquid Membranes from The Industrial Wastewater. Chem Eng Process. 2022; 173: 108812. https://doi.org/10.1016/j.cep.2022.108812
Sundararaman S, Aravind Kumar J, Deivasigamani P, Devarajan Y. Emerging pharma residue contaminants: Occurrence, monitoring, risk and fate assessment – A challenge to water resource management. Sci Total Environ. 2022; 825: 153897. https://doi.org/10.1016/j.scitotenv.2022.153897
Sgroi M, Anumol T, Vagliasindi FGA, Snyder SA, Roccaro P. Comparison of the new Cl2/O3/UV process with different ozone- and UV-based AOPs for wastewater treatment at pilot scale: Removal of pharmaceuticals and changes in fluorescing organic matter. Sci Total Environ. 2021; 765: 142720. https://doi.org/10.1016/j.scitotenv.2020.142720
Gadipelly C, Pérez-González A, Yadav GD, Ortiz I, Ibáñez R, Rathod VK, Marathe KV. Pharmaceutical Industry Wastewater: Review of the Technologies for Water Treatment and Reuse. Ind Eng Chem Res. 2014; 53(29): 11571-11592. https://doi.org/10.1021/ie501210j
Florindo C, Monteiro NV, Ribeiro BD, Branco LC, Marrucho IM. Hydrophobic deep eutectic solvents for purification of water contaminated with Bisphenol-A. J Mol Liq. 2020; 297: 111841. https://doi.org/10.1016/j.molliq.2019.111841
Florindo C, Lima F, Branco LC, Marrucho IM. Hydrophobic Deep Eutectic Solvents: A Circular Approach to Purify Water Contaminated with Ciprofloxacin. ACS Sustain Chem Eng. 2019; 7(17): 14739-14746. https://doi.org/10.1021/acssuschemeng.9b02658
Qu Q, Lv Y, Liu L, Row KH, Zhu T. Synthesis and characterization of deep eutectic solvents (five hydrophilic and three hydrophobic), and hydrophobic application for microextraction of environmental water samples. Anal Bioanal Chem. 2019; 411(28): 7489-7498. https://doi.org/10.1007/s00216-019-02143-z
Florindo C, Branco LC, Marrucho IM. Development of hydrophobic deep eutectic solvents for extraction of pesticides from aqueous environments. Fluid Phase Equilibr. 2017; 448: 135-142. https://doi.org/10.1016/j.fluid.2017.04.002
Ge D, Wang Y, Jianga Q, Dai E. A Deep Eutectic Solvent as an Extraction Solvent to Separate and Preconcentrate Parabens in Water Samples Using in situ Liquid-Liquid Microextraction. J Brazil Chem Soc. 2019; 30(6): 1203-1210. https://doi.org/10.21577/0103-5053.20190014
Elgharbawy AAM, Hayyan A, Hayyan M, Mirghani MES, Salleh HM, Rashid SN, Ngoh GC, Liew SQ, Nor MR, bin Mohd Yusoff MYZ, Alias Y. Natural Deep Eutectic Solvent-Assisted Pectin Extraction from Pomelo Peel Using Sonoreactor: Experimental Optimization Approach. Processes. 2019; 7(7). https://doi.org/10.3390/pr7070416
Al-Risheq DIM, Nasser MS, Qiblawey H, Ba-Abbad MM, Benamor A, Hussein IA. Destabilization of stable bentonite colloidal suspension using choline chloride based deep eutectic solvent: Optimization study. J Water Process Eng. 2021; 40: 101885. https://doi.org/10.1016/j.jwpe.2020.101885
Al-Risheq DIM, Nasser MS, Qiblawey H, Hussein IA, Benamor A. Choline chloride based natural deep eutectic solvent for destabilization and separation of stable colloidal dispersions. Sep Purif Technol. 2021; 255: 117737. https://doi.org/10.1016/j.seppur.2020.117737
Klamt A. COSMO-RS: From Quantum Chemistry to Fluid Phase Thermodynamics and Drug Design. 1st ed., Amsterdam, Netherlands: Elsevier; 2005.
Foong CY, Zulkifli MFM, Wirzal MDH, Bustam MA, Nor LHM, Saad MS, Abd Halim NS. COSMO-RS prediction and experimental investigation of amino acid ionic liquid-based deep eutectic solvents for copper removal. J Mol Liq. 2021; 333: 115884. https://doi.org/10.1016/j.molliq.2021.115884
Hu W, Shang Z, Wei N, Hou B, Gong J, Wang Y. Solubility of benorilate in twelve monosolvents: Determination, correlation and COSMO-RS analysis. J Chem Thermodyn. 2021; 152: 106272. https://doi.org/10.1016/j.jct.2020.106272
Khan AS, Ibrahim TH, Rashid Z, Khamis MI, Nancarrow P, Jabbar NA. COSMO-RS based screening of ionic liquids for extraction of phenolic compounds from aqueous media. J Mol Liq. 2021; 328: 115387. https://doi.org/10.1016/j.molliq.2021.115387