Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers

Main Article Content

Svetlana Vito Dmitrović
Marija Prekajski
Bojan Jokić
Goran Branković
Aleksandra Zarubica
Vladimir Žikić
Branko Matović

Abstract

Spider silk fibers, collected from Pholcus Phalangioides spider were used as a template for obtaining magnesium oxide (MgO, periclase) as well as magnesium hydroxide (Mg(OH)2, brucite) fibers. Magnesium oxide fibers were obtained in a simple manner by heat induced decomposition of magnesium salt (MgCl2) in the presence of the spider silk fibers, while magnesium hydroxidefibers were synthesized by hydration of MgO fibers at 50 °C, 70°C and 90 °C, for 48 and 96 h. According to Scanning electron microscopy (SEM), dimensions of spider silk fibers determined the dimension of synthesized MgO fibers, while for Mg(OH)2 fibers, the average diameter was increased with prolonging the hydration period. The surface of Mg(OH)2 fibers was noticed to be covered with brucite in a form of plates. X-ray diffraction (XRD) analysis showed that MgO fibers were single-phased (the pure magnesium oxide fibers were obtained), while Mg(OH)2 fibers were two- or single-phased brucite depending on incubation period, and/or incubation temperature.

Article Details

How to Cite
[1]
S. V. Dmitrović, “Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers”, Hem Ind, vol. 72, no. 1, pp. 23–28, Jan. 2018, doi: 10.2298/HEMIND170404018D.
Section
Applied Chemistry

How to Cite

[1]
S. V. Dmitrović, “Spider silk as a template for obtaining magnesium oxide and magnesium hydroxide fibers”, Hem Ind, vol. 72, no. 1, pp. 23–28, Jan. 2018, doi: 10.2298/HEMIND170404018D.

References

Morales E, Lunsford JH. Oxidative dehydrogenation of ethane over a lithium-promoted magnesium oxide catalyst J Catal 1989; 118 (1): 255-265.

Nagaraja BM, Kumar VS, Shashikala V, Padmasri AH, Sreevardhan Reddy SS, Raju BD, Rama Rao KS. Effect of method of preparation of copper – magnesium oxide catalyst on the dehydrogenation of cyclohexanol. J Mol Catal A: Chem. 2004; 223: 339-345.

Guzman J, Gates BC. Structure and Reactivity of a Mononuclear Gold-Complex Catalyst Supported on Magnesium Oxide. Angew Chem Int Ed. 2003; 42(6): 690-693.

Oelerich W, Klassen T, Bormann R. Metal oxides as catalysts for improved hydrogen sorption in nanocrystalline Mg-based materials. J Alloys and Compd. 2001; 315 (1–2): 237-242.

Kumar D, Reddy VB, Mishra BG, Rana RK, Nadagouda MN, Varma RS. Nanosized magnesium oxide as catalyst for the rapid and green synthesis of substituted 2-amino-2-chromenes. Tetrahedron. 2007; 63(15): 3093-3097.

Copp A. Magnesia/magnesite. Am Ceram Soc bull. 1995; 74(6): 135-137.

Yin D, Zhang Y, Zhang Y, Peng Z, Fan Y, Sun K. Reinforcement of peroxide-cured styrene–butadiene rubber vulcanizates by mathacrylic acid and magnesium oxide. J Appl Polym Sci. 2002; 85(13): 2667-2676.

Bhargava A, Alarco JA, Mackinnon IDR, Page D, Ilyushechkin A. Synthesis and characterisation of nanoscale magnesium oxide powders and their application in thick films of Bi2Sr2CaCu2O8. Mater Lett. 1998; 34(3–6): 133-142.

Yuan YS, Wong MS, Wang SS. Solid-state processing and phase development of bulk (MgO)w/BPSCCO high-temperature superconducting composite. J Mater Res. 1996. 11(1): 8-17.

Chen D. Zhu L, Liu P, Zhang H, Xu K, Chen M. Rod-like morphological magnesium hydroxide and magnesium oxide via a wet coprecipitation process. J Porous Mater. 2009; 16(1): 13-18.

Kordas G. Sol-gel preparation of MgO fibers. J Mater Chem. 2000; 10(5): 1157-1160.

Chen YJ, Li JB, Han YS, Yang XY, Dai JH. Fabrication of decorated MgO crystalline fibers. Mater Res Bull. 2003; 38(3), 445-452.

Hota G, Ramakrishna S, WunJern N. One step fabrication of MgO solid and hollow submicrometar fibers via Electrospining method. Am Ceram Soc. 2009; 92(10) 2429-2433.

Rocha SDF, Mansur MB, Ciminelli VST. Kinetics and mechanistic analysis of caustic magnesia hydration. J Chem Technol Biotechnol. 2004; 79(8): 816-821.

Holloway LR. Application of Magnesium Hydroxide as a Flame Retardant and Smoke Suppressant in Elastomers. Rubber Chem Technol. 1988; 61(2): 186-193.

Rocha SDF, Ciminelli VST. Utilization of Magnesium Hydroxide Produced by Magnesia Hydration as Fire Retardant for Nylon 6-6,6. Polímeros. 2001; 11: 116-120.

Lv J, Qiu L,Qu B. Controlled growth of three morphologicalstructures of magnesium hydroxide nanoparticles by wet precipitation method. J Cryst Growth. 2004; 267(3-4): 676-684.

Lv J, Qiu L, Qu B. Controlled synthesis of magnesium hydroxide nanoparticles with different morphological structures and related properties in flame retardant ethylene-vinyl acetate blends. Nanotechnology. 2004; 15: 1576.

Yan C, Xue D, Zou L, Yan X, Wang W. Preparation of magnesium hydroxide nanoflowers. J Cryst Growth. 2005; 282(3-4): 448-454.

Annal GH, Kamath V. Electrochemical synthesis of metal oxides and hydroxides. Chem Mater. 2000; 12(5): 1195-1204.

Li Y, Sui M, Ding Y, Zhuang J, Wang C. Preparation of Mg(OH)2 nanorods. Adv Mater. 2000; 12: 818-821.

Hao L, Zhu C, Mo X, Jiang W, Hu Y, Zhu Y, Chen Z. Preparation and characterization of Mg(OH)2 nanorods by liquid-solid arc discharge technique. Inorg Chem Commun. 2003; 6(3): 229-232.

Zou G, Liu R, Chen W. Highly textural lamellar mesostructured magnesium hydroxide via a catodic electrodeposition process. Mater Lett. 2007; 61(10): 1990-1993.

Doblhofer E, Heidebrecht A, Scheibel T. To spin or not to spin: spider silk fibers and more. Appl Microbiol Biotechnol. 2015; 99(22): 9361-9380.

Singh A, Hede S, Sastry M. Spider Silk as an Active Scaffold in the Assembly of Gold Nanoparticles and Application of the Gold–Silk Bioconjugate in Vapor Sensing. Small. 2007; 3(3): 466-473.

Mayes EL, Vollrath F, Mann S. Fabrication of Magnetic Spider Silk and Other Silk-Fiber Composites Using Inorganic Nanoparticles. Adv Mater. 1998; 10(10): 801-805.

Huang L, Wang H, Hayashi CY, Tian B, Zhao D, Yan Y. Single-strand spider silk templating for the formation of hierarchically ordered hollow mesoporous silica fibers. J Mater Chem. 2003; 13(4): 666-668.

Yan L, Zhuang J, Sun X, Deng Z, Li Y. Formation of rod-like Mg(OH)(2) nanocrystallites under hydrothermal conditions and the conversion to MgO nanorods by thermal dehydration. Mater Chem Phys. 2002; 76(2): 119-122.

Razouk R, Mikhail RS. The hydration of magnesium oxide from the vapor phase. J Phys Chem. 1958; 62(8): 920-925.

Henrist C, Mathieu JP, Vogels C, Rulmont A, Cloots R. Morphological study of magnesium hydroxide nanoparticles precipitated in dilute aqueous solution. J Cryst Growth. 2003; 249(1–2): 321-330.

Fan W, Sun S, Song X, Zhang W, Yu H, Tan X, Cao G. Controlled synthesis of single-crystalline Mg(OH)2 nanotubes and nanorods via a solvothermal process. J Solid State Chem. 2004; 177(7): 2329-2338.

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