LIGHT OLEFIN PRODUCTION USING THE MIXTURE OF HZSM-5/MCM-41 AND -Al2O3 AS CATALYSTS FOR CATALYTIC PYROLYSIS OF WASTE TIRES

Article Sidebar

Cover
PDF (1,388 kB)
Published: Apr 25, 2021
DOI: https://doi.org/10.2298/CICEQ200302025F
Keywords:
catalytic pyrolysis, HZSM-5, light olefins, MCM-41, MCM-41, waste tires, γ-Al2O3

Main Article Content

RURU FU
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, PR China
ZHUANGZHANG HE
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, PR China
SHIKAI QIN
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, PR China
QINGZE JIAO
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, PR China and School of Materials and Environment, Beijing Institute of Technology, Zhuhai, Guangdong, PR China
CAIHONG FENG
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, PR China
HANSHENG LI
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, PR China
YUN ZHAO
School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, PR China

Abstract

In this paper, micro-mesoporous HZSM-5/MCM-41 zeolites were prepared by a two-step hydrothermal method using commercial HZSM-5 with two different silica/alumina ratios (38 and 50) as starting materials. The structures, morpho­logies and acidity of as-prepared zeolites were analyzed using XRD, FT-IR, SEM, N2-adsorption/desorption and NH3-TPD. The HZSM-5/MCM-41 zeolites combined the acidity of microporous HZSM-5 with the pore advantages of mesoporous MCM-41. Mesopores and microspores of 3.34 and 0.95 nm in diameter were found to be present in HZSM-5/MCM-41 zeolites. When they were used to catalyze the pyrolysis of waste tires, the selectivity of light olefins for HZSM-5/MCM-41 prepared using HZSM-5 with the silica/alumina ratio of 50 as starting materials was 21.42%, higher than 18.43% of HZSM-5/MCM-41 syn­the­sized using HZSM-5 with the silica/alumina ratio of 38. In order to further overcome the pore size constraints and mass transfer limitations of HZSM-5/MCM-41 zeolites for catalyzing pyrolysis of waste tires, macroporous
γ-Al2O3 were mixed with HZSM-5/MCM-41 and used as catalysts. The select­ivity to light olefins for the mixture of γ-Al2O3 and HZSM-5/MCM-41 prepared using HZSM-5 with the silica/alumina ratio of 50 as starting materials was 33.65%, which was obviously enhanced by the introduction of γ-Al2O3.

Article Details

How to Cite
FU, R. ., HE, Z. ., QIN, S. ., JIAO, Q. ., FENG, C. ., LI, H. ., & ZHAO, Y. . (2021). LIGHT OLEFIN PRODUCTION USING THE MIXTURE OF HZSM-5/MCM-41 AND -Al2O3 AS CATALYSTS FOR CATALYTIC PYROLYSIS OF WASTE TIRES. Chemical Industry & Chemical Engineering Quarterly, 27(1), 69–78. https://doi.org/10.2298/CICEQ200302025F
Issue
Vol. 27 No. 1 (2021)
Section
Articles

Authors who publish with this journal agree to the following terms:

Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.

Authors grant to the Publisher the following rights to the manuscript, including any supplemental material, and any parts, extracts or elements thereof:

  • the right to reproduce and distribute the Manuscript in printed form, including print-on-demand;
  • the right to produce prepublications, reprints, and special editions of the Manuscript;
  • the right to translate the Manuscript into other languages;
  • the right to reproduce the Manuscript using photomechanical or similar means including, but not limited to photocopy, and the right to distribute these reproductions;
  • the right to reproduce and distribute the Manuscript electronically or optically on any and all data carriers or storage media – especially in machine readable/digitalized form on data carriers such as hard drive, CD-Rom, DVD, Blu-ray Disc (BD), Mini-Disk, data tape – and the right to reproduce and distribute the Article via these data carriers; 
  • the right to store the Manuscript in databases, including online databases, and the right of transmission of the Manuscript in all technical systems and modes;
  • the right to make the Manuscript available to the public or to closed user groups on individual demand, for use on monitors or other readers (including e-books), and in printable form for the user, either via the internet, other online services, or via internal or external networks.

References

D.N. Anh, K. Raweewan, W. Sujitra, J. Sirirat, J. Anal. Appl. Pyrolysis 86 (2009) 281-286

J.M. Lee, J.S. Lee, Energy 20 (1996) 969-976

G. Lopez, M. Olazar, M. Amutio, R. Aguado, J. Bilbao, Energy Fuels 23 (2009) 5423-5431

P.T. Williams, Waste Manage. 33 (2013) 1714-1728

A.M. Fernández, C. Barriocanal, R. Alvarez, J. Hazard. Mater. 203-204 (2012) 236-243

J.P. Falkenhagen, L. Maisonneuve, P.P. Paalanen, N. Coste, N. Malicki, B.M. Weckhuysen, Chem.Eur.J. 24 (2018) 4597-4606

S. Abbasizadeh, R. Karimzadeh, Ind. Eng. Chem. Res. 57 (2018) 7783-7794

K. Sana, P. Maria, T. Mohand, K. Besma, Z. Fethi, J Energy Resour. Technol. 139 (2016) 032203

S.S.Z. Salmasi, M.S. Abbas-Abadi, M.N. Haghighi, H. Abedini, Fuel 160 (2015) 544-548

B. Shen, C. Wu, C. Liang, B. Guo, R. Wang, J. Anal. Appl. Pyrolysis 78 (2007) 243-249

B. Shen, C. Wu, B. Guo, R. Wang, C. Liang, Appl. Catal., B 73 (2007) 150-157

G.S. Miguel, J. Aguado, D.P. Serrano, J.M. Escola, Appl. Catal., B 64 (2006) 209-219

J. Zheng, Q. Zeng, Y. Yi, Y. Wang, J. Ma, B. Qin, X. Zhang, W. Sun, R. Li, Catal. Today 168 (2011) 124-132

J. Shah, M.R. Jan, F. Mabood, Energy Convers. Manage. 50 (2009) 991-994

S. Kotrel, H.G.C. Knozinger Microporous Mesoporous Mater. 35-36 (2000) 11-20

X. Li, B. Shen, C. Xu, Appl. Catal., A 375 (2010) 222-229

C. Witpathomwong, R. Longloilert, S. Wongkasemjit, S. Jitkarnka, Energy Procedia 9 (2011) 245-251

W. Namchot, S. Jitkarnka, J. Anal. Appl. Pyrolysis 121 (2016) 297-306

Z. Li, Z. Zhong, B. Zhang, W. Wang, W. Wu, J. Anal. Appl. Pyrolysis 138 (2019) 103-113

Y. Sang, Q. Jiao, H. Li, Q. Wu, Y. Zhao, K. Sun, J. Nanopart. Res. 16 (2014) 2755

T. Fu, R. Qi, W. Wan, J. Shao, J.Z. Wen, Z. Li, ChemCatChem 9 (2017) 4212-4224

Z. Ma, T. Fu, Y. Wang, J. Shao, Q. Ma, C. Zhang, L. Cui, Z. Li, Ind. Eng. Chem. Res. 58 (2019) 2146-2158

R.A. Nadkarni, Anal. Chem. 52 (1980) 929-935

H. Li, S. He, K. Ma, Q. Wu, Q. Jiao, K. Sun, Appl. Catal., A 450 (2013) 152-159

F.G. Denardin, O.W. Perez-Lopez, Microporous Mesoporous Mater. 295 (2020) 109961

Y.F. Yeong, A.Z. Abdullah, S.B.A. Latif Ahmad, Microporous Mesoporous Mater. 123 (2009) 129-139

Y. Luo, P. Yang, J. Lin, Microporous Mesoporous Mater. 111 (2008) 194-199

K. Ding, Z. Zhong, B. Zhang, J. Wang, A. Min, R. Ruan, J. Anal. Appl. Pyrolysis 122 (2016) 55-63

Y. Gu, N. Cui, Q. Yu, C. Li, Q. Cui, Appl. Catal., A 429-430 (2012) 9-16

A.S. Al-Dughaither, H. de Lasa, Ind. Eng. Chem. Res. 53 (2014) 15303-15316

D. Ma, W. Zhang, Y. Shu, X. Liu, Y. Xu, X. Bao, Catal. Lett. 66 (2000) 155-160

Y.G.A.J. Scott Buchanan, Appl. Catal., A 134 (1996) 247-262

C. Berrueco, E. Esperanza, F.J. Mastral, J. Ceamanos, P. García-Bacaicoa, J. Anal. Appl. Pyrolysis 74 (2005) 245-253

S. Muenpol, R. Yuwapornpanit, S. Jitkarnka, Clean Technol. Environ. Policy 17 (2016) 1149–1159

M. Olazar, M. Arabiourrutia, G. López, R. Aguado, J. Bilbao, J. Anal. Appl. Pyrolysis 82 (2008) 199-204

M. Arabiourrutia, M. Olazar, R. Aguado, G.L. Pez, A. Bar¬ona, J. Bilbao, Ind. Eng. Chem. Res. 47 (2008) 7600–7609

Z. He, Q. Jiao, Z. Fang, T. Li, C. Feng, H. Li, Y. Zhao, J. Anal. Appl. Pyrolysis 129 (2018) 66-71

C. Wang, X. Tian, B. Zhao, L. Zhu, S. Li, Processes 7 (2019) 335.