Determination of isotopic distribution of lead by a matrix assisted laser desorption/ionization versus a laser desorption/ionization time of flight mass spectrometry

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Tina T. Kamčeva
Maja D. Nešić
Milovan M. Stoiljković
Iva A. Popović
Jadranka N. Miletić
Boris M. Rajčić
Marijana Ž. Petković
Suzana R. Veličković

Abstract

In this work it has been shown that both the laser desorption/ionization mass spectro­metry (LDI MS) and the matrix assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI TOF MS) are the simple and quick methods for determination of relative natural isotopic distribution of lead. The analysis of metal salts with these appro­aches does not require any time-consuming preparation of samples: a single run can take only a minute, and numerous information can be obtained. Results obtained in this work show that chosen matrix has no negative effect on quantitative determination of lead isotopes and support once more the applicability of MALDI TOF MS for lead isotope dis­tribution determination in the sample and accurate data are obtained. Additionally, the generation of PbnOn and PbnOn–1 (n: 2–6) clusters have been successfully achieved in the positive mode, using the both LDI and MALDI methods. All stoichiometries were confirmed using isotopic pattern modelling.

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How to Cite
Kamčeva, T. T., Nešić, M. D., Stoiljković, M. M., Popović, I. A., Miletić, J. N., Rajčić, B. M., Petković, M. Ž., & Veličković, S. R. (2017). Determination of isotopic distribution of lead by a matrix assisted laser desorption/ionization versus a laser desorption/ionization time of flight mass spectrometry. HEMIJSKA INDUSTRIJA (Chemical Industry), 71(1), 19–26. https://doi.org/10.2298/HEMIND151218013K
Section
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References

A.O. Nier, Variations in the Relative Abundances of the Isotopes of Common Lead from Various Sources, J. Am. Chem. Soc. 60 (1938) 1571–1576.

J.S. Stacey, W.J. Moore, R.D. Rubright, Precision mea-surement of lead isotopes ratios: preliminary analyses from the U.S. mine, Bingham Canyon, Utah, Earth Planet. Sc. Lett. 2 (1967) 489–499.

D. De Muynck, C. Cloquet, F. Vanhaecke, Development of a new method for Pb isotopic analysis of archaeo¬logical artefacts using single-collector ICP-dynamic reac¬tion cell-MS, J. Anal. Atom. Spectrom. 23 (2008) 62–71.

A.J. Loveless, Lead isotopes — a guide to major mineral deposits, Geoexploration 13 (1975) 13–27.

G.L. Cumming, J.R. Richards, Ore lead isotope ratios in a continuously changing Earth, Earth Planet. Sci. Lett. 28 (1975) 155–171.

C. Gariépy, C.J. Allègre, The lead isotope geochemistry and geochronology of late-kinematic intrusives from the Abitibi greenstone belt, and the implications for late Archaean crustal evolution, Geochim. Cosmochim. Acta 49 (1985) 2371–2383.

H. Cheng, Y. Hu, Lead (Pb) isotopic fingerprinting and its applications in lead pollution studies in China: A review, Environ. Pollut. 158 (2010) 1134–1146.

Y. Hao, Z. Guo, Z. Yang, D. Fan, M. Fang, X. Li, Tracking historical lead pollution in the coastal area adjacent to the Yangtze River Estuary using lead isotopic compo-sitions, Environ. Pollut. 156 (2008) 1325–1331.

K-E. Sjåstad, S.L. Simonsen,T. Andersen, Use of lead isotopic ratios to discriminate glass samples in forensic science, J. Anal. Atom. Spectrom. 26 (2011) 325–333.

J.R. Dean, L. Ebdon, R.C. Massey, Isotope ratio and isotope dilution analysis of lead in wine by inductively coupled plasma – mass spectrometry, Food Addit. Contam. 7 (1990) 109–116.

H. Barton, Z. Zachwieja, S. D'llio, S. Caroli, Application of routine estimation of Pb isotopic ratios by inductively coupled plasma mass spectrometry for studying the Pb origin in hair of children living in polluted areas. A pilot study, Microchem. J. 67 (2000) 21–30.

J.D. Cremin, M.L. Luck, N.K. Laughlin, D.R. Smith, Efficacy of Succimer Chelation for Reducing Brain Lead in a Pri¬mate Model of Human Lead Exposure, Toxicol. Appl. Pharm. 161 (1999) 283–293.

M. Krummen, A.W. Hilkert, D. Juchelka, A. Duhr, H. Schlüter, R. Pesch, A new concept for isotope ratio monitoring liquid chromatography/mass spectrometry, Rapid. Commun. Mass Spectrom. 18 (2004) 2260–2266.

W. Weckwerth, L. Willmitzer, O. Fiehn, Comparative quantification and identification of phosphoproteins using stable isotope labeling and liquid chromato-graphy/mass spectrometry, Rapid. Commun. Mass Spec¬trom. 14 (2000) 1677–1681.

L.M. Thienpont, C. Fierens, A.P. De Leenheer, L. Przywara, Isotope dilution-gas chromatography/mass spectrometry and liquid chromatography/electrospray ionization-tandem mass spectrometry for the deter-mination of triiodo-L-thyronine in serum, Rapid. Commun. Mass Spectrom. 13 (1999) 1924–1931.

G.J. Bowen, L. Chesson, K. Nielson, T.E. Cerling, J.R. Ehleringer, Treatment methods for the determination of δ2H and δ18O of hair keratin by continuous-flow iso¬tope-ratio mass spectrometry, Rapid. Commun. Mass Spectrom. 19 (2005) 2371–2378.

R.M. Rao, A.R. Parab, K.S. Bhushan, S. K. Aggarwal, High precision isotope ratio measurements on boron by thermal ionization mass spectrometry using Rb2BO2+ ion, Anal. Methods 3 (2011) 322–327.

H. Gerstenberger, G. Haase, A highly effective emitter substance for mass spectrometric Pb isotope ratio determinations, Chem. Geol. 136 (1997) 309–312.

C. Pomiès, A. Cocherie, C. Guerrot, E. Marcoux, J. Lancelot, Assessment of the precision and accuracy of lead–isotope ratios measured by TIMS for geochemical applications: example of massive sulphide deposits (Rio Tinto, Spain), Chem. Geol. 144 (1998) 137–149.

J. Bettmer, Application of isotope dilution ICP-MS techniques to quantitative proteomics, Anal. Bioanal. Chem. 397 (2010) 3495–3502.

L.V. Miller, K.M. Hambidge, P.V. Fennessey, Analytical considerations in trace metal isotope analysis using fast atom bombardment–induced ionization, Anal. Chim. Acta 241 (1990) 249–254.

G.G. Dolnikowski, J.T. Watson, J. Allison, Direct deter-mination of metals in archeological artifacts by fast atom bombardment mass spectrometry, Anal. Chem. 56 (1984) 197–201.

H. Seyama, Application of SIMS to the analysis of envi-ronmental samples, Appl. Surf. Sci. 203–204 (2003) 745–

–750.

M. Miyabe, M. Oba, M. Kato, I. Wakaida, K. Watanabe, Development of RIMS Apparatus for Isotope Analysis of Calcium in Nuclear Waste Materials, J. Nucl. Sci. Technol. 43 (2006) 305–310.

H.P. Longerich, B.J. Fryer, D.F. Strong, Determination of lead isotope ratios by inductively coupled plasma–mass spectrometry (ICP-MS), Spectrochim. Acta, B 42 (1987) 39–48.

I. Horn, R.L.Rudnick, W.F. McDonough, Precise ele-mental and isotope ratio determination by simultaneous solution nebulization and laser ablation-ICP-MS: appli¬cation to U-Pb geochronology, Chem.Geol. 164 (2000) 281–301.

W.M. White, F. Albarède, P. Télouk, High-precision analysis of Pb isotope ratios by multi-collector ICP-MS, Chem.Geol. 167 (2000) 257–270.

M. Barbaste, L. Halicz, A. Galy, B. Medina, H. Emteborg, F.C. Adams, R. Lobinski, Evaluation of the accuracy of the determination of lead isotope ratios in wine by ICP MS using quadrupole, multicollector magnetic sector and time-of-flight analyzers, Talanta 54 (2001) 307–317.

V. Ettler, M. Mihaljevič, M. Komárek, ICP-MS measure-ments of lead isotopic ratios in soils heavily contam-inated by lead smelting: tracing the sources of pollution, Anal. Bioanal. Chem. 378 (2004) 311–317.

A.S. Medel, M.M. Bayon, M.R. Fernandez de la Campa, J.R. Encionar, J. Bettmer, Elemental mass spectrometry for quantitave proteomics, Anal. Bioanal. Chem. 390 (2008) 3–16.

J.G. Morison, P. White, S. McDougall, J.W. Firth, S.G. Woolfrey, M.A. Graham, D. Greenslade, Validation of a highly sensitive ICP-MS method for the determination of platinum in biofluids: application to clinical pharmaco-kinetic studies with oxaliplatin, J.Pharm. Biomed. Anal. 24 (2000) 1–10.

W. Henderson J.S. McIndoe, Mass Spectrometry of Inorganic, Coordination and Organometallic Com¬pounds, John Wiley & Sons Ltd., London, 2005.

K. Minakata, H. Nozawa, I. Yamagishi, K. Gonmori, M. Suzuki, K. Hasegawa, A. Wurita, K. Watanabe, O. Suzuki, MALDI-Q-TOF mass spectrometric determination of gold and platinum in tissues using their diethyldithio¬car¬bamate chelate complexes, Anal. Bioanal. Chem. 406 (2014) 1331–1338.

R. Zenobi, R. Knochenmuss, Ion formation in MALDI mass spectrometry, Mass Spectrom. Rev. 17 (1998) 337–366.

B. Damnjanović, T. Kamčeva, B. Petrović, Ž.D. Bugarčić and M. Petković, Laser desorption and ionization time-

-of-flight versus matrix-assisted laser desorption and ionization time-of-flight mass spectrometry of Pt(II) and Ru(III) metal complexes, Anal. Methods 3 (2011) 400–

–407.

Y.C. Liu, C.K. Chiang, H.T. Chang, Y.F. Lee, C.C. Huang, Using a Functional Nanogold Membrane Coupled with Laser Desorption/Ionization Mass Spectrometry to Det-ect Lead Ions in Biofluids, Adv. Funct. Mater. 21 (2011) 4448–4455.

B. Damjanović, B. Petrović, J. Dimitrić-Marković, M. Petković, Comparison of MALDI-TOF mass spectra of [PdCl(dien)]Cl and [Ru(en)2Cl2]Cl acquired with different matrices, J. Serb. Chem. Soc. 76 (2011) 1687–1700.

T. Kamčeva, J. Flemmig, B. Damnjanović, J. Arnhold, A. Mijatović, M. Petković, Inhibitory effect of platinum and ruthenium bipyridyl complexes on porcine pancreatic phospholipase A2, Metallomics 3 (2011) 1056–1063.

M. Radisavljević, T. Kamčev, I. Vukićević, M. Nišavić, M. Milovanović, M. Petković, Sensitivity and accuracy of organic mtrix-assisted laser desorption and ionization mass spectrometry of FeCl3 is higher than in matrix-free approach, Eur. J. Mass Spectrom. 19 (2013) 77–89.

K.J.R. Rasman, R.D.P. Taylor, Isotopic compositions of the elements, Pure Appl. Chem. 70 (1998) 217–235.

F. Hillenkamp, J. Peter-Katalinic, MALDI MS: A Practical Guide to Instrumentation, Methods and Applications, 2nd ed., Wiley-Blackwell, New York, 2013

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